{"created":"2021-03-01T06:35:09.268637+00:00","id":27179,"links":{},"metadata":{"_buckets":{"deposit":"ffe717ca-c5e4-4c94-8802-ebd8e0d096e6"},"_deposit":{"id":"27179","owners":[],"pid":{"revision_id":0,"type":"depid","value":"27179"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00027179","sets":["1917:1918:1919"]},"author_link":["89074","89075","89076","89077","89078","89079"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-11-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"11","bibliographicPageEnd":"15424","bibliographicPageStart":"15419","bibliographicVolumeNumber":"6","bibliographic_titles":[{"bibliographic_title":"ACS Sustainable Chemistry & Engineering","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Amines in heteroaromatic systems and pharmaceutical intermediates were functionalized through N-methylation with methanol using a palladium-loaded titanium dioxide (Pd/TiO2) photocatalyst. This method provides access to a series of tertiary N-methylamines bearing N-, O-, and/or S-containing heteroaromatic functionalities from primary/secondary amines and methanol under mild reaction conditions. Facile syntheses of several pharmaceuticals containing N-methyl or ethyl groups, as well as related deuterated drugs, was achieved through the late-stage functionalization of amines.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2019-11-05","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acssuschemeng.8b03855","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Sustainable Chemistry & Engineering], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-G2mCKTXg7y5BCEnWAmU9].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_62":{"attribute_name":"ISSN（Online）","attribute_value_mlt":[{"subitem_source_identifier":"2168-0485","subitem_source_identifier_type":"EISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Wang, Lyu-Ming","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89074","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Jenkinson, Kellie","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89075","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Wheatley, Andrew E. H.","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89076","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kuwata, Keiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89077","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Saito, Susumu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89078","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Naka, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89079","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-11-05"}],"displaytype":"detail","filename":"Pd_8926.pdf","filesize":[{"value":"714.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Pd_8926","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/27179/files/Pd_8926.pdf"},"version_id":"a4134096-0e31-417b-bd11-652f59e0a6a8"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Green chemistry","subitem_subject_scheme":"Other"},{"subitem_subject":"Methanol","subitem_subject_scheme":"Other"},{"subitem_subject":"Methylation","subitem_subject_scheme":"Other"},{"subitem_subject":"Pharmaceuticals","subitem_subject_scheme":"Other"},{"subitem_subject":"Photocatalysis","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Photocatalytic N-Methylation of Amines over Pd/TiO2 for the Functionalization of Heterocycles and Pharmaceutical Intermediates","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Photocatalytic N-Methylation of Amines over Pd/TiO2 for the Functionalization of Heterocycles and Pharmaceutical Intermediates","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1919"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-03-06"},"publish_date":"2019-03-06","publish_status":"0","recid":"27179","relation_version_is_last":true,"title":["Photocatalytic N-Methylation of Amines over Pd/TiO2 for the Functionalization of Heterocycles and Pharmaceutical Intermediates"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:50:37.195355+00:00"}