@article{oai:nagoya.repo.nii.ac.jp:00027209,
 author = {Ohki, Yasuhiro and Uchida, Keisuke and Hara, Ryota and Kachi, Mami and Fujisawa, Mayu and Tada, Mizuki and Sakai, Yoichi and Sameera, W. M. C.},
 issue = {64},
 journal = {Chemistry – A European Journal},
 month = {Nov},
 note = {A synthetic protocol was developed for a series of cubane‐type [Mo3S4M] clusters that incorporate halides of first‐row transition metals (M) from Groups 4–10. This protocol is based on the anionic cluster platform [Cp^*3Mo3S4]^− ([1]^−; Cp^*=η^5‐C5Me5), which crystallizes when K(18‐crown‐6) is used as the counter cation. Treatment of in situ‐generated [1]^− with such transition‐metal halides led to the formation of [Mo3S4M] clusters, in which the M/halide ratio gradually changes from 1:2 to 1:1.5 and to 1:1, when moving from early to late transition metals. This trend suggests a tendency for early transition metals to tolerate higher oxidation states and adopt larger ionic radii relative to late transition metals. The properties of the [Mo3S4Fe] cluster 6 a were investigated in detail by using 57Fe Mössbauer spectroscopy and computational methods., ファイル公開：2019-11-16},
 pages = {17138--17147},
 title = {Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum},
 volume = {24},
 year = {2018}
}