{"created":"2021-03-01T06:35:11.244877+00:00","id":27209,"links":{},"metadata":{"_buckets":{"deposit":"0158a58e-a100-444b-899f-5a316665268f"},"_deposit":{"id":"27209","owners":[],"pid":{"revision_id":0,"type":"depid","value":"27209"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00027209","sets":["336:695:696"]},"author_link":["89138","89139","89140","89141","89142","89143","89144","89145"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-11-16","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"64","bibliographicPageEnd":"17147","bibliographicPageStart":"17138","bibliographicVolumeNumber":"24","bibliographic_titles":[{"bibliographic_title":"Chemistry – A European Journal","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A synthetic protocol was developed for a series of cubane‐type [Mo3S4M] clusters that incorporate halides of first‐row transition metals (M) from Groups 4–10. This protocol is based on the anionic cluster platform [Cp^*3Mo3S4]^− ([1]^−; Cp^*=η^5‐C5Me5), which crystallizes when K(18‐crown‐6) is used as the counter cation. Treatment of in situ‐generated [1]^− with such transition‐metal halides led to the formation of [Mo3S4M] clusters, in which the M/halide ratio gradually changes from 1:2 to 1:1.5 and to 1:1, when moving from early to late transition metals. This trend suggests a tendency for early transition metals to tolerate higher oxidation states and adopt larger ionic radii relative to late transition metals. The properties of the [Mo3S4Fe] cluster 6 a were investigated in detail by using 57Fe Mössbauer spectroscopy and computational methods.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2019-11-16","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/chem.201804083","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [Y. Ohki, K. Uchida, R. Hara, M. Kachi, M. Fujisawa, M. Tada, Y. Sakai, W. M. C. Sameera, Chem. Eur. J. 2018, 24, 17138.], which has been published in final form at [https://doi.org/10.1002/chem.201804083]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0947-6539","subitem_source_identifier_type":"PISSN"}]},"item_10_source_id_62":{"attribute_name":"ISSN（Online）","attribute_value_mlt":[{"subitem_source_identifier":"1521-3765","subitem_source_identifier_type":"EISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ohki, Yasuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89138","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Uchida, Keisuke","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89139","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hara, Ryota","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89140","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kachi, Mami","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89141","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fujisawa, Mayu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89142","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tada, Mizuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89143","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakai, Yoichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89144","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sameera, W. M. C.","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89145","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-11-16"}],"displaytype":"detail","filename":"accepted_Mo3S4M_manuscript_CEJ.pdf","filesize":[{"value":"1.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"accepted_Mo3S4M_manuscript_CEJ","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/27209/files/accepted_Mo3S4M_manuscript_CEJ.pdf"},"version_id":"e70f85e7-02f2-4398-9039-973a80ec6830"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"clusters","subitem_subject_scheme":"Other"},{"subitem_subject":"cubane","subitem_subject_scheme":"Other"},{"subitem_subject":"first-row transition metals","subitem_subject_scheme":"Other"},{"subitem_subject":"molybdenum","subitem_subject_scheme":"Other"},{"subitem_subject":"sulfur","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-03-07"},"publish_date":"2019-03-07","publish_status":"0","recid":"27209","relation_version_is_last":true,"title":["Cubane‐Type [Mo3S4M] Clusters with First‐Row Groups 4–10 Transition‐Metal Halides Supported by C5Me5 Ligands on Molybdenum"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:18:32.331052+00:00"}