{"created":"2021-03-01T06:35:59.284378+00:00","id":27948,"links":{},"metadata":{"_buckets":{"deposit":"0eecf8ab-8678-43ce-9d52-26ebfd44323e"},"_deposit":{"id":"27948","owners":[],"pid":{"revision_id":0,"type":"depid","value":"27948"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00027948","sets":["1917:1918:1919"]},"author_link":["90991","90992","90993","90994","90995","90996","90997"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"143","bibliographicPageStart":"138","bibliographicVolumeNumber":"8","bibliographic_titles":[{"bibliographic_title":"Asian Journal of Organic Chemistry","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Regioselective C−H arylation using pentavalent organoantimony compounds as a new class of arylating reagents is described. The reaction of thiophenes with triarylantimony difluorides in the presence of 5 mol% of Pd(OAc)2 and 2 equiv. CuCl2 at 80 °C under aerobic conditions afforded the β‐arylated thiophene derivatives in moderate‐to‐high yields. The reaction is sensitive to the electronic nature of the triarylantimony difluorides – those bearing an electron‐donating group on the phenyl ring showed higher reactivity than those have an electron‐withdrawing group.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2020-01-01","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/ajoc.201800654","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":" \t\"This is the peer reviewed version of the following article: [Y. Kitamura, Y. Murata, A. Oguri, M. Matsumura, N. Kakusawa, H. Naka, S. Yasuike, Asian J. Org. Chem. 2019, 8, 138.], which has been published in final form at [https://doi.org/10.1002/ajoc.201800654]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\"","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_62":{"attribute_name":"ISSN（Online）","attribute_value_mlt":[{"subitem_source_identifier":"2193-5807","subitem_source_identifier_type":"EISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kitamura, Yuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"90991","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Murata, Yuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"90992","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Oguri, Ayaka","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"90993","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsumura, Mio","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"90994","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kakusawa, Naoki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"90995","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Naka, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"90996","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yasuike, Shuji","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"90997","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-01"}],"displaytype":"detail","filename":"AJOC181113_3.pdf","filesize":[{"value":"448.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AJOC181113_3","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/27948/files/AJOC181113_3.pdf"},"version_id":"0e99f951-9af7-41df-afe0-cdbdd5958df0"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Antimony","subitem_subject_scheme":"Other"},{"subitem_subject":"Thiophene","subitem_subject_scheme":"Other"},{"subitem_subject":"Palladium catalyst","subitem_subject_scheme":"Other"},{"subitem_subject":"Pentavalent triarylantimony difluoride","subitem_subject_scheme":"Other"},{"subitem_subject":"β-selective C−H arylation","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Pd‐Catalyzed β‐Selective C−H Arylation of Thiophenes with Triarylantimony Difluorides","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Pd‐Catalyzed β‐Selective C−H Arylation of Thiophenes with Triarylantimony Difluorides","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1919"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-05-09"},"publish_date":"2019-05-09","publish_status":"0","recid":"27948","relation_version_is_last":true,"title":["Pd‐Catalyzed β‐Selective C−H Arylation of Thiophenes with Triarylantimony Difluorides"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:50:38.331170+00:00"}