{"created":"2021-03-01T06:36:16.382757+00:00","id":28208,"links":{},"metadata":{"_buckets":{"deposit":"6ed113d7-4552-4691-98f5-11c85ba0a52b"},"_deposit":{"id":"28208","owners":[],"pid":{"revision_id":0,"type":"depid","value":"28208"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00028208","sets":["320:321:322"]},"author_link":["91818","91819","91820"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-02-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"473","bibliographicPageStart":"465","bibliographicVolumeNumber":"57","bibliographic_titles":[{"bibliographic_title":"Journal of Polymer Science Part A: Polymer Chemistry","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In this work, we examined the synthesis of novel block (co)polymers by mechanistic transformation through anionic, cationic, and radical living polymerizations using terminal carbon–halogen bond as the dormant species. First, the direct halogenation of growing species in the living anionic polymerization of styrene was examined with CCl4 to form a carbon–halogen terminal, which can be employed as the dormant species for either living cationic or radical polymerization. The mechanistic transformation was then performed from living anionic polymerization into living cationic or radical polymerization using the obtained polymers as the macroinitiator with the SnCl4/n‐Bu4NCl or RuCp*Cl(PPh3)/Et3N initiating system, respectively. Finally, the combination of all the polymerizations allowed the synthesis block copolymers including unprecedented gradient block copolymers composed of styrene and p‐methylstyrene. ","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2020-02-01","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/pola.29261","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [Satoh, K. , Mori, Y. and Kamigaito, M. (2019), Direct through anionic, cationic, and radical active species: Terminal carbon–halogen bond for “controlled”/living polymerizations of styrene. J. Polym. Sci. Part A: Polym. Chem., 57: 465-473. doi:10.1002/pola.29261], which has been published in final form at [https://doi.org/10.1002/pola.29261]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0887-624X","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Satoh, Kotaro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"91818","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mori, Yuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"91819","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kamigaito, Masami","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"91820","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-02-01"}],"displaytype":"detail","filename":"JOURNAL_OF_POLYMER_SCIENCE_PART_A_57_3_2019_465-473.pdf","filesize":[{"value":"2.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JOURNAL_OF_POLYMER_SCIENCE_PART_A_57_3_2019_465-473","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/28208/files/JOURNAL_OF_POLYMER_SCIENCE_PART_A_57_3_2019_465-473.pdf"},"version_id":"50d44419-4b4e-44de-acf1-594ae0953fc1"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"carbon–halogen bond","subitem_subject_scheme":"Other"},{"subitem_subject":"living anionic polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"living cationic polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"living radical polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"mechanistic transformation","subitem_subject_scheme":"Other"},{"subitem_subject":"styrene","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Direct through anionic, cationic, and radical active species: Terminal carbon–halogen bond for “controlled”/living polymerizations of styrene","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Direct through anionic, cationic, and radical active species: Terminal carbon–halogen bond for “controlled”/living polymerizations of styrene","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-06-07"},"publish_date":"2019-06-07","publish_status":"0","recid":"28208","relation_version_is_last":true,"title":["Direct through anionic, cationic, and radical active species: Terminal carbon–halogen bond for “controlled”/living polymerizations of styrene"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:20:35.987546+00:00"}