{"created":"2021-03-01T06:36:16.845001+00:00","id":28215,"links":{},"metadata":{"_buckets":{"deposit":"03440fec-3d9a-4bcc-95bd-2d45159b62f4"},"_deposit":{"id":"28215","owners":[],"pid":{"revision_id":0,"type":"depid","value":"28215"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00028215","sets":["320:321:322"]},"author_link":["91857","91858","91859"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-02-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"1881","bibliographicPageStart":"1877","bibliographicVolumeNumber":"141","bibliographic_titles":[{"bibliographic_title":"Journal of the American Chemical Society","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"This paper describes the isolation and characterization of an aromatic radical cation generated by FeCl3. X-ray crystallographic analysis and kinetic studies reveal the mechanism of the generation of aromatic radical cation. In the solid state, a tight ion-pair of a radical cation with FeCl4^– is observed. Leveraging the efficient generation of the radical cation–FeCl4^– ion pair, we explore a radical cation-induced cycloaddition of trans-anethole initiated by catalytic amount of FeCl3. Both [4+2] cycloaddition and [2+2] cycloaddition with a broad substrate scope are also described. Moreover, a 100 g-scale reaction is demonstrated with the use of 1 mol % of FeCl3 as a simple and a highly active initiator.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2020-02-06","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/jacs.8b12827","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-KpstntDrJeZDzRJWKebU].” ","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0002-7863","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Horibe, Takahiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"91857","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ohmura, Shuhei","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"91858","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishihara, Kazuaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"91859","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-02-06"}],"displaytype":"detail","filename":"manuscript20190611.pdf","filesize":[{"value":"12.7 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"manuscript20190611","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/28215/files/manuscript20190611.pdf"},"version_id":"ff67a449-3df0-49cb-927f-09f9ef018022"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Structure and Reactivity of Aromatic Radical Cations Generated by FeCl3","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Structure and Reactivity of Aromatic Radical Cations Generated by FeCl3","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-06-11"},"publish_date":"2019-06-11","publish_status":"0","recid":"28215","relation_version_is_last":true,"title":["Structure and Reactivity of Aromatic Radical Cations Generated by FeCl3"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:20:39.608372+00:00"}