{"created":"2021-03-01T06:36:26.109722+00:00","id":28354,"links":{},"metadata":{"_buckets":{"deposit":"47a977ce-0418-4435-a141-9bbab4762a9a"},"_deposit":{"id":"28354","owners":[],"pid":{"revision_id":0,"type":"depid","value":"28354"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00028354","sets":["320:321:322"]},"author_link":["92673","92674","92675","92676","92677"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-05-16","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"81","bibliographicPageStart":"76","bibliographicVolumeNumber":"723","bibliographic_titles":[{"bibliographic_title":"Chemical Physics Letters","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have investigated chemical forms of molybdenum ion in nitric acid solution, using liquid-phase X-ray absorption fine structure, ultraviolet–visible absorption spectroscopy and first-principles calculations, from a viewpoint of disposal of high-level radioactive nuclear liquid wastes. The experimental and theoretical results indicated that Mo is a hexavalent ion and forms a hexa-coordination binuclear-structured complex in the 2M nitic acid solution. The predominant chemical species of Mo complexes in the 2M nitric acid solution (which is used for HLLW) are assigned to be [Mo2O5(H2O)6]^2+ and [Mo2O4(OH)(H2O)6]^3+. These species may play a crucial role of forming so-called yellow-phase in vitrified objects.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021-05-16","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.cplett.2019.02.049","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0009-2614","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Watanabe, Shinta","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"92673","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sato, Toshikazu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"92674","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakaya, Masato","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"92675","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yoshida, Tomoko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"92676","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Onoe, Jun","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"92677","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-05-16"}],"displaytype":"detail","filename":"manuscript.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"manuscript","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/28354/files/manuscript.pdf"},"version_id":"cdecdab0-3039-47c9-b7fa-68af18f3b96e"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Molybdenum","subitem_subject_scheme":"Other"},{"subitem_subject":"XAFS","subitem_subject_scheme":"Other"},{"subitem_subject":"First-principles calculations","subitem_subject_scheme":"Other"},{"subitem_subject":"High-level radioactive nuclear liquid wastes","subitem_subject_scheme":"Other"},{"subitem_subject":"Vitrification processes","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Chemical forms of molybdenum ion in nitric acid solution studied using liquid-phase X-ray absorption fine structure, Ultraviolet–Visible absorption spectroscopy and first-principles calculations","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Chemical forms of molybdenum ion in nitric acid solution studied using liquid-phase X-ray absorption fine structure, Ultraviolet–Visible absorption spectroscopy and first-principles calculations","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-07-12"},"publish_date":"2019-07-12","publish_status":"0","recid":"28354","relation_version_is_last":true,"title":["Chemical forms of molybdenum ion in nitric acid solution studied using liquid-phase X-ray absorption fine structure, Ultraviolet–Visible absorption spectroscopy and first-principles calculations"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:21:00.460282+00:00"}