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Synthesis of a hydrogen-bridged tetraborane(6): a substituent effect of a diaminoboryl group toward the B–B multiple bond character
http://hdl.handle.net/2237/00030591
http://hdl.handle.net/2237/00030591227345f0-a475-4444-9c6e-56f72a61c006
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-08-09 | |||||
タイトル | ||||||
タイトル | Synthesis of a hydrogen-bridged tetraborane(6): a substituent effect of a diaminoboryl group toward the B–B multiple bond character | |||||
言語 | en | |||||
著者 |
Yagi, Atsumi
× Yagi, Atsumi× Kisu, Haruki× Yamashita, Makoto |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
抄録 | ||||||
内容記述 | A hydrogen-bridging tetraborane(6) was synthesized from boryllithium, a boron nucleophile, in three steps. The structural and spectroscopic analyses of the tetraborane(6) revealed σ-donor and π-acceptor effects of diaminoboryl substituents toward the central B–B moiety having a multiple bond character. DFT calculations also supported the experimentally observed substituent effect of the boryl group. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2020-05-07 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Royal Society of Chemistry | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1039/C9DT01117J | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1477-9226 | |||||
書誌情報 |
en : Dalton Transactions 巻 48, 号 17, p. 5496-5499, 発行日 2019-05-07 |
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著者版フラグ | ||||||
値 | author |