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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Synthesis of a hydrogen-bridged tetraborane(6): a substituent effect of a diaminoboryl group toward the B–B multiple bond character

http://hdl.handle.net/2237/00030591
227345f0-a475-4444-9c6e-56f72a61c006
名前 / ファイル ライセンス アクション
20190318_Text_rev.pdf 20190318_Text_rev (755.2 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2019-08-09
タイトル
タイトル Synthesis of a hydrogen-bridged tetraborane(6): a substituent effect of a diaminoboryl group toward the B–B multiple bond character
著者 Yagi, Atsumi

× Yagi, Atsumi

WEKO 92921

Yagi, Atsumi

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Kisu, Haruki

× Kisu, Haruki

WEKO 92922

Kisu, Haruki

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Yamashita, Makoto

× Yamashita, Makoto

WEKO 92923

Yamashita, Makoto

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抄録
内容記述 A hydrogen-bridging tetraborane(6) was synthesized from boryllithium, a boron nucleophile, in three steps. The structural and spectroscopic analyses of the tetraborane(6) revealed σ-donor and π-acceptor effects of diaminoboryl substituents toward the central B–B moiety having a multiple bond character. DFT calculations also supported the experimentally observed substituent effect of the boryl group.
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2020-05-07
内容記述タイプ Other
出版者
出版者 Royal Society of Chemistry
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1039/C9DT01117J
ISSN(print)
収録物識別子タイプ ISSN
収録物識別子 1477-9226
書誌情報 Dalton Transactions

巻 48, 号 17, p. 5496-5499, 発行日 2019-05-07
著者版フラグ
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