{"created":"2021-03-01T06:36:35.659659+00:00","id":28501,"links":{},"metadata":{"_buckets":{"deposit":"c8f3b259-8fdf-4b6e-b18d-2158a2852a2d"},"_deposit":{"id":"28501","owners":[],"pid":{"revision_id":0,"type":"depid","value":"28501"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00028501","sets":["320:321:322"]},"author_link":["93478","93479","93480","93481","93482","93483","93484","93485"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-05-14","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"3341","bibliographicPageStart":"3327","bibliographicVolumeNumber":"52","bibliographic_titles":[{"bibliographic_title":"Macromolecules","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A series of sequence-regulated vinyl copolymers with high-order and long vinyl monomer sequences were constructed via a combination of iterative single vinyl monomer additions, which were mediated by radical and cationic intermediates, and subsequent metal-catalyzed step-growth radical polymerization. The construction of vinyl monomer sequences was attained by iterative single monomer radical and cationic additions between a dichloride, having a similar substituent to that of vinyl monomers, and vinyl monomers such as styrenes, acrylates, and acrylonitrile. The resulting products were converted into sequence-regulated ab-type monomers that have embedded vinyl monomer sequences between an unconjugated C═C bond and reactive C–Cl bond via selective allylation of one of the two C–Cl bonds at their terminals. The synthesized sequence-regulated ab-type monomers were polymerized via metal-catalyzed step-growth radical polymerization, which resulted in vinyl chloride units via repetitive intermolecular addition reactions between the C═C and C–Cl terminals. Alternatively, aa- and bb-type sequence-regulated monomers, which have two unconjugated C═C and two reactive C–Cl bonds, respectively, were prepared by similar iterative single monomer additions and were subsequently polymerized via metal-catalyzed step-growth radical polymerization. The repeating vinyl monomer sequence codes in the resulting polymers, such as ABCC, ABCD, ABBAC, ABDBAC, and ABDBACAEEAC, varied from 4 to 11 monomer units in which the embedded vinyl monomer units were styrenes, acrylates, acrylamides, acrylonitrile, vinyl chloride, vinylidene chloride, and ethylene.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.macromol.9b00676","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Macromolecules], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-YPWWeB4KgQ4yxA4GqzIs].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0024-9297","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Satoh, Kotaro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"93478","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishizuka, Kenta","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"93479","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hamada, Tsuyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"93480","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Handa, Masato","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"93481","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Abe, Tomohiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"93482","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ozawa, Satoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"93483","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Miyajima, Masato","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"93484","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kamigaito, Masami","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"93485","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-05-14"}],"displaytype":"detail","filename":"MACROMOLECULES_52_9_2019_3327-3341.pdf","filesize":[{"value":"1.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"MACROMOLECULES_52_9_2019_3327-3341","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/28501/files/MACROMOLECULES_52_9_2019_3327-3341.pdf"},"version_id":"0f9e86ee-5e31-444b-bc28-2b5e09800819"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-09-17"},"publish_date":"2019-09-17","publish_status":"0","recid":"28501","relation_version_is_last":true,"title":["Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:20:52.587233+00:00"}