{"created":"2021-03-01T06:36:43.660832+00:00","id":28622,"links":{},"metadata":{"_buckets":{"deposit":"e3d9f2b2-75ec-4fbc-8ba2-5f2f97ae2218"},"_deposit":{"id":"28622","owners":[],"pid":{"revision_id":0,"type":"depid","value":"28622"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00028622"},"item_10_biblio_info_6":{"attribute_name":"\u66f8\u8a8c\u60c5\u5831","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-06-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"32","bibliographicPageEnd":"7622","bibliographicPageStart":"7618","bibliographicVolumeNumber":"25","bibliographic_titles":[{"bibliographic_title":"Chemistry \u2013 A European Journal"}]}]},"item_10_description_4":{"attribute_name":"\u6284\u9332","attribute_value_mlt":[{"subitem_description":"The synthesis of antiaromatic Ni^II\u2013norcorroles having primary, secondary, and tertiary alkyl groups at the reactive meso\u2010positions was attempted. Reductive coupling of a Ni^II\u2013dipyrrin precursor provided Ni^II\u2013meso\u2010dihexylnorcorrole, which underwent substantial degradation on silica gel. Introduction of tert\u2010butyl groups was unsuccessful due to the difficult preparation of the corresponding dipyrrin precursor. Meanwhile, Ni^II\u2013norcorroles with isopropyl and cyclohexyl groups were isolated as stable molecules under ambient conditions. Furthermore, we found that oxidation of Ni^II\u2013meso\u2010dialkylnorcorroles with hydrogen peroxide in the presence of sodium carbonate gave Ni^II\u20135\u2010oxaporphyrins(2.0.1.0). In contrast, oxidation of Ni^II\u2013meso\u2010dimesitylnorcorrole under the same reaction conditions gave 10\u2010oxaporphyrin(1.1.1.0). The contrasting reactivity can be attributed to the steric congestion around the meso\u2010positions.","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"\u5185\u5bb9\u8a18\u8ff0","attribute_value_mlt":[{"subitem_description":"\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2020-06-07","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"\u51fa\u7248\u8005","attribute_value_mlt":[{"subitem_publisher":"Wiley"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/chem.201901292","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"\u6a29\u5229","attribute_value_mlt":[{"subitem_rights":"\"This is the peer reviewed version of the following article: [S.-Y. Liu, H. Tanaka, R. Nozawa, N. Fukui, H. Shinokubo, Chem. Eur. J. 2019, 25, 7618.], which has been published in final form at [https://doi.org/10.1002/chem.201901292]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]},"item_10_select_15":{"attribute_name":"\u8457\u8005\u7248\u30d5\u30e9\u30b0","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN\uff08print\uff09","attribute_value_mlt":[{"subitem_source_identifier":"0947-6539","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"\u8457\u8005","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Liu, Si\u2010Yu"}],"nameIdentifiers":[{"nameIdentifier":"93717","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tanaka, Hiroko"}],"nameIdentifiers":[{"nameIdentifier":"93718","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nozawa, Ryo"}],"nameIdentifiers":[{"nameIdentifier":"93719","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukui, Norihito"}],"nameIdentifiers":[{"nameIdentifier":"93720","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shinokubo, Hiroshi"}],"nameIdentifiers":[{"nameIdentifier":"93721","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"\u30d5\u30a1\u30a4\u30eb\u60c5\u5831","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-06-07"}],"displaytype":"detail","filename":"alkyl_norcorrole0419.pdf","filesize":[{"value":"2.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"alkyl_norcorrole0419","url":"https://nagoya.repo.nii.ac.jp/record/28622/files/alkyl_norcorrole0419.pdf"},"version_id":"52287baf-0ed7-4c95-a9b2-5b133fde438e"}]},"item_language":{"attribute_name":"\u8a00\u8a9e","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"\u8cc7\u6e90\u30bf\u30a4\u30d7","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of meso-Alkyl-Substituted Norcorrole\u2013Ni^II Complexes and Conversion to 5-Oxaporphyrins (2.0.1.0)","item_titles":{"attribute_name":"\u30bf\u30a4\u30c8\u30eb","attribute_value_mlt":[{"subitem_title":"Synthesis of meso-Alkyl-Substituted Norcorrole\u2013Ni^II Complexes and Conversion to 5-Oxaporphyrins (2.0.1.0)"}]},"item_type_id":"10","owner":"1","path":["320/321/322"],"pubdate":{"attribute_name":"\u516c\u958b\u65e5","attribute_value":"2019-10-16"},"publish_date":"2019-10-16","publish_status":"0","recid":"28622","relation_version_is_last":true,"title":["Synthesis of meso-Alkyl-Substituted Norcorrole\u2013Ni^II Complexes and Conversion to 5-Oxaporphyrins (2.0.1.0)"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2021-03-01T09:58:22.758599+00:00"}