{"created":"2021-03-01T06:36:47.513601+00:00","id":28682,"links":{},"metadata":{"_buckets":{"deposit":"ca70a3cc-ef11-4224-aae6-83790ebc0bcd"},"_deposit":{"id":"28682","owners":[],"pid":{"revision_id":0,"type":"depid","value":"28682"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00028682","sets":["320:321:322"]},"author_link":["94145","94146"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-08-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"15","bibliographicPageEnd":"2882","bibliographicPageStart":"2878","bibliographicVolumeNumber":"38","bibliographic_titles":[{"bibliographic_title":"Organometallics","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A Ni(II) 10-boracorrole (2) was obtained from the transmetalation of the corresponding 10-silacorrole with BBr3. The antiaromaticity of 2 was examined by 1H NMR spectroscopy and theoretical calculations. The antiaromatic character of 2 is reflected in a very narrow HOMO–LUMO gap that results in weak and broad absorption bands in the NIR region up to 1800 nm. Furthermore, titration experiments revealed a high Lewis acidity of 2 toward pyridines. Theoretical calculations on 2 indicated the presence of p−π^* conjugation, which significantly stabilizes the energy level of its LUMO.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2020-08-12","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.organomet.9b00303","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-S9f4xWKW8p566Ss4DYjy].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0276-7333","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Omori, Hiroto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94145","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shinokubo, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94146","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-08-12"}],"displaytype":"detail","filename":"Bcorrole_revised.pdf","filesize":[{"value":"2.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Bcorrole_revised","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/28682/files/Bcorrole_revised.pdf"},"version_id":"adce7e3e-aac0-43ac-af23-61e23d1d8c30"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Ni(II) 10-Boracorrole: An Antiaromatic Porphyrinoid Containing a Boron Atom at the meso-Position","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Ni(II) 10-Boracorrole: An Antiaromatic Porphyrinoid Containing a Boron Atom at the meso-Position","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-11-13"},"publish_date":"2019-11-13","publish_status":"0","recid":"28682","relation_version_is_last":true,"title":["Ni(II) 10-Boracorrole: An Antiaromatic Porphyrinoid Containing a Boron Atom at the meso-Position"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:21:23.712250+00:00"}