@article{oai:nagoya.repo.nii.ac.jp:00028692, author = {Lu, Xuanming and Kanamori, Kazuyoshi and Nakanishi, Kazuki}, issue = {29}, journal = {New Journal of Chemistry}, month = {Aug}, note = {A facile method for the preparation of zinc oxide with three-dimensionally (3D) interconnected macropores has been developed. The Zn-based monolithic gel was obtained using citric acid (CA) as a structure supporter via an epoxide-mediated sol–gel method accompanied by phase separation. The size of the macropores could be controlled by the ratio of methanol to propylene oxide in the starting solution. The Zn-based gel was heat-treated in air with the purpose of removing the organic components and crystallizing the ZnO, finally resulting in pure ZnO (purity >90%, with negligible carbon content) with 3D interconnected macropores and an open nanoscale network. The influence of the starting solvent composition on the Zn-based gel morphologies has been examined and discussed based on the chemical compatibility of the Zn–CA complex with other components., ファイル公開:2020/08/07}, pages = {11720--11726}, title = {Preparation of zinc oxide with a three-dimensionally interconnected macroporous structure via a sol–gel method accompanied by phase separation}, volume = {43}, year = {2019} }