@article{oai:nagoya.repo.nii.ac.jp:00028693, author = {Shibuya, Masatoshi and Kawano, Shohei and Fujita, Shoji and Yamamoto, Yoshihiko}, issue = {7}, journal = {Asian Journal of Organic Chemistry}, month = {Jul}, note = {B(C6F5)3‐catalyzed tandem double hydrofunctionalization reactions initiated by intramolecular hydroamination of unactivated alkynes are described herein. In the hydroamination/hydroallylation reaction, in situ preparation of anhydrous B(C6F5)3 from B(C6F5)3 ⋅ nH2O and the use of 2,6‐di‐tert‐butylphenol as a proton source were effective. In the hydroamination/hydrocyanation reaction, a combination of B(C6F5)3 ⋅ nH2O and H2O as the proton source provided good results., ファイル公開:2020/07/01}, pages = {1075--1079}, title = {Boron‐Catalyzed Hydroamination/Hydroallylation and Hydroamination/Hydrocyanation of Unactivated Alkynes}, volume = {8}, year = {2019} }