{"_buckets": {"deposit": "d76e51fa-3451-42ff-b094-6f778ac26180"}, "_deposit": {"id": "28836", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "28836"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00028836"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-10-14", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "42", "bibliographicPageEnd": "15035", "bibliographicPageStart": "15031", "bibliographicVolumeNumber": "58", "bibliographic_titles": [{"bibliographic_title": "Angewandte Chemie International Edition"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A pincer\u2010iridium complex bearing a Lewis\u2010base\u2010free X\u2010type alumanyl ligand has been synthesized. X\u2010ray diffraction, NMR and IR spectroscopy, as well as XANES analysis confirmed its tetrahydrido\u2010Ir^V structure and Lewis acidity at the Al center as supported by DFT calculations. The resulting complex was applied as a catalyst for the transfer dehydrogenation of cyclooctane.", "subitem_description_type": "Abstract"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": " https://doi.org/10.1002/anie.201909009", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [S. Morisako, S. Watanabe, S. Ikemoto, S. Muratsugu, M. Tada, M. Yamashita, Angew. Chem. Int. Ed. 2019, 58, 15031.], which has been published in final form at [https://doi.org/10.1002/anie.201909009]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "14337851", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Morisako, Shogo"}], "nameIdentifiers": [{"nameIdentifier": "94897", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Watanabe, Seiya"}], "nameIdentifiers": [{"nameIdentifier": "94898", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ikemoto, Satoru"}], "nameIdentifiers": [{"nameIdentifier": "94899", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Muratsugu, Satoshi"}], "nameIdentifiers": [{"nameIdentifier": "94900", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tada, Mizuki"}], "nameIdentifiers": [{"nameIdentifier": "94901", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamashita, Makoto"}], "nameIdentifiers": [{"nameIdentifier": "94902", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-10-14"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Text_20190809.pdf", "filesize": [{"value": "729.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 729600.0, "url": {"label": "Text_20190809", "url": "https://nagoya.repo.nii.ac.jp/record/28836/files/Text_20190809.pdf"}, "version_id": "589d0c17-4dab-4e02-9132-83f1d4be298a"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "alumanyl ligands", "subitem_subject_scheme": "Other"}, {"subitem_subject": "homogeneous catalysis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "iridium", "subitem_subject_scheme": "Other"}, {"subitem_subject": "pincer complex", "subitem_subject_scheme": "Other"}, {"subitem_subject": "XANES", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00031023", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2019-12-19"}, "publish_date": "2019-12-19", "publish_status": "0", "recid": "28836", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes"], "weko_shared_id": null}