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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes

http://hdl.handle.net/2237/00031023
fb315670-b731-4179-8f58-d869c40e846e
名前 / ファイル ライセンス アクション
Text_20190809.pdf Text_20190809 (729.6 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2019-12-19
タイトル
タイトル Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes
著者 Morisako, Shogo

× Morisako, Shogo

WEKO 94897

Morisako, Shogo

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Watanabe, Seiya

× Watanabe, Seiya

WEKO 94898

Watanabe, Seiya

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Ikemoto, Satoru

× Ikemoto, Satoru

WEKO 94899

Ikemoto, Satoru

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Muratsugu, Satoshi

× Muratsugu, Satoshi

WEKO 94900

Muratsugu, Satoshi

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Tada, Mizuki

× Tada, Mizuki

WEKO 94901

Tada, Mizuki

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Yamashita, Makoto

× Yamashita, Makoto

WEKO 94902

Yamashita, Makoto

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権利
権利情報 "This is the peer reviewed version of the following article: [S. Morisako, S. Watanabe, S. Ikemoto, S. Muratsugu, M. Tada, M. Yamashita, Angew. Chem. Int. Ed. 2019, 58, 15031.], which has been published in final form at [https://doi.org/10.1002/anie.201909009]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions."
キーワード
主題Scheme Other
主題 alumanyl ligands
キーワード
主題Scheme Other
主題 homogeneous catalysis
キーワード
主題Scheme Other
主題 iridium
キーワード
主題Scheme Other
主題 pincer complex
キーワード
主題Scheme Other
主題 XANES
抄録
内容記述 A pincer‐iridium complex bearing a Lewis‐base‐free X‐type alumanyl ligand has been synthesized. X‐ray diffraction, NMR and IR spectroscopy, as well as XANES analysis confirmed its tetrahydrido‐Ir^V structure and Lewis acidity at the Al center as supported by DFT calculations. The resulting complex was applied as a catalyst for the transfer dehydrogenation of cyclooctane.
内容記述タイプ Abstract
出版者
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/anie.201909009
ISSN(print)
収録物識別子タイプ ISSN
収録物識別子 14337851
書誌情報 Angewandte Chemie International Edition

巻 58, 号 42, p. 15031-15035, 発行日 2019-10-14
著者版フラグ
値 author
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