@article{oai:nagoya.repo.nii.ac.jp:00028836, author = {Morisako, Shogo and Watanabe, Seiya and Ikemoto, Satoru and Muratsugu, Satoshi and Tada, Mizuki and Yamashita, Makoto}, issue = {42}, journal = {Angewandte Chemie International Edition}, month = {Oct}, note = {A pincer‐iridium complex bearing a Lewis‐base‐free X‐type alumanyl ligand has been synthesized. X‐ray diffraction, NMR and IR spectroscopy, as well as XANES analysis confirmed its tetrahydrido‐Ir^V structure and Lewis acidity at the Al center as supported by DFT calculations. The resulting complex was applied as a catalyst for the transfer dehydrogenation of cyclooctane.}, pages = {15031--15035}, title = {Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes}, volume = {58}, year = {2019} }