{"created":"2021-03-01T06:36:57.569997+00:00","id":28836,"links":{},"metadata":{"_buckets":{"deposit":"d76e51fa-3451-42ff-b094-6f778ac26180"},"_deposit":{"id":"28836","owners":[],"pid":{"revision_id":0,"type":"depid","value":"28836"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00028836","sets":["320:321:322"]},"author_link":["94897","94898","94899","94900","94901","94902"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-10-14","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"42","bibliographicPageEnd":"15035","bibliographicPageStart":"15031","bibliographicVolumeNumber":"58","bibliographic_titles":[{"bibliographic_title":"Angewandte Chemie International Edition","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A pincer‐iridium complex bearing a Lewis‐base‐free X‐type alumanyl ligand has been synthesized. X‐ray diffraction, NMR and IR spectroscopy, as well as XANES analysis confirmed its tetrahydrido‐Ir^V structure and Lewis acidity at the Al center as supported by DFT calculations. The resulting complex was applied as a catalyst for the transfer dehydrogenation of cyclooctane.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201909009","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [S. Morisako, S. Watanabe, S. Ikemoto, S. Muratsugu, M. Tada, M. Yamashita, Angew. Chem. Int. Ed. 2019, 58, 15031.], which has been published in final form at [https://doi.org/10.1002/anie.201909009]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"14337851","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Morisako, Shogo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94897","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Watanabe, Seiya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94898","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ikemoto, Satoru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94899","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Muratsugu, Satoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94900","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tada, Mizuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94901","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamashita, Makoto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94902","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-10-14"}],"displaytype":"detail","filename":"Text_20190809.pdf","filesize":[{"value":"729.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Text_20190809","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/28836/files/Text_20190809.pdf"},"version_id":"589d0c17-4dab-4e02-9132-83f1d4be298a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"alumanyl ligands","subitem_subject_scheme":"Other"},{"subitem_subject":"homogeneous catalysis","subitem_subject_scheme":"Other"},{"subitem_subject":"iridium","subitem_subject_scheme":"Other"},{"subitem_subject":"pincer complex","subitem_subject_scheme":"Other"},{"subitem_subject":"XANES","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-12-19"},"publish_date":"2019-12-19","publish_status":"0","recid":"28836","relation_version_is_last":true,"title":["Synthesis of A Pincer-IrV Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:21:55.619780+00:00"}