{"_buckets": {"deposit": "9ac68f3b-11db-471a-91fb-3b55359dacaa"}, "_deposit": {"id": "28840", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "28840"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00028840"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-08-21", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "16", "bibliographicPageEnd": "3743", "bibliographicPageStart": "3739", "bibliographicVolumeNumber": "361", "bibliographic_titles": [{"bibliographic_title": "Advanced Synthesis \u0026 Catalysis"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Difluoromethyl\u2010substituted allylic phosphates were synthesized from 2\u2010cycloalkenones through the addition of a (difluoromethyl)phosphonate and subsequent phospha\u2010Brook rearrangement. The obtained allylic phosphates were converted to the corresponding difluoromethyl\u2010substituted cycloalkenes using the Cu\u2010mediated SN2\u2019 reaction of Grignard or organolithium reagents.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2020-08-21", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/adsc.201900469", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [Y. Yamamoto, Y. Ishida, Y. Takamizu, T. Yasui, Adv. Synth. Catal. 2019, 361, 3739.], which has been published in final form at [https://doi.org/10.1002/adsc.201900469]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1615-4150", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yamamoto, Yoshihiko"}], "nameIdentifiers": [{"nameIdentifier": "94915", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishida, Yuki"}], "nameIdentifiers": [{"nameIdentifier": "94916", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Takamizu, Yosuke"}], "nameIdentifiers": [{"nameIdentifier": "94917", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yasui, Takeshi"}], "nameIdentifiers": [{"nameIdentifier": "94918", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-08-21"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "MS_ASC_Rev1.pdf", "filesize": [{"value": "465.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 465100.0, "url": {"label": "MS_ASC_Rev1", "url": "https://nagoya.repo.nii.ac.jp/record/28840/files/MS_ASC_Rev1.pdf"}, "version_id": "fc1f570f-3510-4540-a595-f0027240ac92"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Fluorine", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Phosphorus", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Copper", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Cycloalkenone", "subitem_subject_scheme": "Other"}, {"subitem_subject": "(Difluoromethyl)alkene", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of (Difluoromethyl)cycloalkenes from 2\u2010Cycloalkenones by Utilizing Phospha\u2010Brook Rearrangement", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis of (Difluoromethyl)cycloalkenes from 2\u2010Cycloalkenones by Utilizing Phospha\u2010Brook Rearrangement"}]}, "item_type_id": "10", "owner": "1", "path": ["1903/1904/1905"], "permalink_uri": "http://hdl.handle.net/2237/00031027", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2019-12-20"}, "publish_date": "2019-12-20", "publish_status": "0", "recid": "28840", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of (Difluoromethyl)cycloalkenes from 2\u2010Cycloalkenones by Utilizing Phospha\u2010Brook Rearrangement"], "weko_shared_id": null}