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Synthesis of (Difluoromethyl)cycloalkenes from 2‐Cycloalkenones by Utilizing Phospha‐Brook Rearrangement
http://hdl.handle.net/2237/00031027
91c9af58-1daf-4e8b-bee3-f2ce4e08fbeb
名前 / ファイル | ライセンス | アクション | |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-12-20 | |||||
タイトル | ||||||
タイトル | Synthesis of (Difluoromethyl)cycloalkenes from 2‐Cycloalkenones by Utilizing Phospha‐Brook Rearrangement | |||||
著者 |
Yamamoto, Yoshihiko
× Yamamoto, Yoshihiko× Ishida, Yuki× Takamizu, Yosuke× Yasui, Takeshi |
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権利 | ||||||
権利情報 | "This is the peer reviewed version of the following article: [Y. Yamamoto, Y. Ishida, Y. Takamizu, T. Yasui, Adv. Synth. Catal. 2019, 361, 3739.], which has been published in final form at [https://doi.org/10.1002/adsc.201900469]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions." | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Fluorine | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Phosphorus | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Copper | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Cycloalkenone | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | (Difluoromethyl)alkene | |||||
抄録 | ||||||
内容記述 | Difluoromethyl‐substituted allylic phosphates were synthesized from 2‐cycloalkenones through the addition of a (difluoromethyl)phosphonate and subsequent phospha‐Brook rearrangement. The obtained allylic phosphates were converted to the corresponding difluoromethyl‐substituted cycloalkenes using the Cu‐mediated SN2’ reaction of Grignard or organolithium reagents. | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2020-08-21 | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
DOI | ||||||
関連識別子 | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/adsc.201900469 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1615-4150 | |||||
書誌情報 |
Advanced Synthesis & Catalysis 巻 361, 号 16, p. 3739-3743, 発行日 2019-08-21 |
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著者版フラグ | ||||||
値 | author |