{"created":"2021-03-01T06:36:58.764402+00:00","id":28854,"links":{},"metadata":{"_buckets":{"deposit":"fc9a85cb-e666-47bc-8a00-ad36a0b88034"},"_deposit":{"id":"28854","owners":[],"pid":{"revision_id":0,"type":"depid","value":"28854"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00028854","sets":["320:321:322"]},"author_link":["94954","94955","94956","94957","94958","94959"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-09-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"33","bibliographicPageEnd":"18137","bibliographicPageStart":"18128","bibliographicVolumeNumber":"21","bibliographic_titles":[{"bibliographic_title":"Physical Chemistry Chemical Physics","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The active sites of Pd/Al2O3 catalysts for CO oxidations were identified by investigating the dependence of CO oxidation activities on the surface structure and morphology of Pd nanoparticles. The maximum catalytic activity was obtained for Pd particles approximately 2 nm in particle size. We performed structural analyses on the Pd surface through infrared (IR) spectroscopy of the adsorbed CO molecules. A positive correlation was obtained between catalytic activity and the fraction of linear CO adsorbed on Pd corner sites and Pd(111) facets, indicating that these sites are highly active for CO oxidation. X-ray absorption fine structure (XAFS) and spherical aberration-corrected scanning transmission electron microscopy (Cs-STEM) measurements demonstrated that Pd nanoparticles less than 2 nm in particle size with amorphous-like structures and Pd particles with large, well-ordered structures favor the formation of a high fraction of corner sites and Pd(111) facets, respectively.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2020/09/07","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1039/C9CP03943K","subitem_relation_type_select":"DOI"}}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"1463-9076","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Murata, Kazumasa","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94954","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Eleeda, Eleen","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94955","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ohyama, Junya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94956","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamamoto, Yuta","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94957","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Arai, Shigeo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94958","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Satsuma, Atsushi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"94959","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-07"}],"displaytype":"detail","filename":"manuscript.pdf","filesize":[{"value":"900.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"manuscript","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/28854/files/manuscript.pdf"},"version_id":"ebaf3091-8622-44ce-a92e-53c87085dbd6"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Pd catalyst","subitem_subject_scheme":"Other"},{"subitem_subject":"CO oxidation","subitem_subject_scheme":"Other"},{"subitem_subject":"particle size effect","subitem_subject_scheme":"Other"},{"subitem_subject":"metal-support interaction","subitem_subject_scheme":"Other"},{"subitem_subject":"alumina","subitem_subject_scheme":"Other"},{"subitem_subject":"surface structure","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Identification of active sites in CO oxidation over a Pd/Al2O3 catalyst","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Identification of active sites in CO oxidation over a Pd/Al2O3 catalyst","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-12-24"},"publish_date":"2019-12-24","publish_status":"0","recid":"28854","relation_version_is_last":true,"title":["Identification of active sites in CO oxidation over a Pd/Al2O3 catalyst"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:59:31.832474+00:00"}