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  1. B300 農学部/生命農学研究科
  2. B300a 雑誌掲載論文
  3. 学術雑誌

Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki–Heck and Intramolecular Diels–Alder Reactions

http://hdl.handle.net/2237/00031173
http://hdl.handle.net/2237/00031173
9696958b-2ffa-418e-95b3-19f1941fa10c
名前 / ファイル ライセンス アクション
revised_main_text.pdf revised_main_text (839.6 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-01-15
タイトル
タイトル Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki–Heck and Intramolecular Diels–Alder Reactions
言語 en
著者 Watanabe, Shogo

× Watanabe, Shogo

WEKO 95200

en Watanabe, Shogo

Search repository
Nishikawa, Toshio

× Nishikawa, Toshio

WEKO 95201

en Nishikawa, Toshio

Search repository
Nakazaki, Atsuo

× Nakazaki, Atsuo

WEKO 95202

en Nakazaki, Atsuo

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-CsaX6tmA87bVW2gfdct6].”
キーワード
主題Scheme Other
主題 Steroids
キーワード
主題Scheme Other
主題 Chemical structure
キーワード
主題Scheme Other
主題 Hydrocarbons
キーワード
主題Scheme Other
主題 Precursors
キーワード
主題Scheme Other
主題 Stereoselectivity
抄録
内容記述 Estrogenic and cardiotonic steroidal skeletons were concisely constructed via Mizoroki–Heck and intramolecular Diels–Alder (IMDA) reactions. Simple modification of the dienophile unsaturation of the IMDA precursor enabled representative AB-ring systems of both steroid classes to be accessed from the same intermediate. The diastereoselectivity of the IMDA reaction used to access the cardiotonic steroidal skeleton was found to be significantly enhanced by performing the reaction in water.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2020-09-20
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1021/acs.orglett.9b02716
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 1523-7060
書誌情報 en : Organic Letters

巻 21, 号 18, p. 7410-7414, 発行日 2019-09-20
著者版フラグ
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