{"_buckets": {"deposit": "6d9f0342-4ba3-499d-b91d-fd61f5b33712"}, "_deposit": {"id": "28986", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "28986"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00028986"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-09-20", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "18", "bibliographicPageEnd": "7414", "bibliographicPageStart": "7410", "bibliographicVolumeNumber": "21", "bibliographic_titles": [{"bibliographic_title": "Organic Letters"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Estrogenic and cardiotonic steroidal skeletons were concisely constructed via Mizoroki\u2013Heck and intramolecular Diels\u2013Alder (IMDA) reactions. Simple modification of the dienophile unsaturation of the IMDA precursor enabled representative AB-ring systems of both steroid classes to be accessed from the same intermediate. The diastereoselectivity of the IMDA reaction used to access the cardiotonic steroidal skeleton was found to be significantly enhanced by performing the reaction in water.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2020-09-20", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.orglett.9b02716", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-CsaX6tmA87bVW2gfdct6].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1523-7060", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Watanabe, Shogo"}], "nameIdentifiers": [{"nameIdentifier": "95200", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishikawa, Toshio"}], "nameIdentifiers": [{"nameIdentifier": "95201", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakazaki, Atsuo"}], "nameIdentifiers": [{"nameIdentifier": "95202", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-09-20"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "revised_main_text.pdf", "filesize": [{"value": "839.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 839600.0, "url": {"label": "revised_main_text", "url": "https://nagoya.repo.nii.ac.jp/record/28986/files/revised_main_text.pdf"}, "version_id": "a1de6509-ef45-4fbd-873c-d4608f3fa84a"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Steroids", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Chemical structure", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Hydrocarbons", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Precursors", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Stereoselectivity", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki\u2013Heck and Intramolecular Diels\u2013Alder Reactions", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki\u2013Heck and Intramolecular Diels\u2013Alder Reactions"}]}, "item_type_id": "10", "owner": "1", "path": ["643/666/667"], "permalink_uri": "http://hdl.handle.net/2237/00031173", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2020-01-15"}, "publish_date": "2020-01-15", "publish_status": "0", "recid": "28986", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki\u2013Heck and Intramolecular Diels\u2013Alder Reactions"], "weko_shared_id": null}