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Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki–Heck and Intramolecular Diels–Alder Reactions
http://hdl.handle.net/2237/00031173
http://hdl.handle.net/2237/000311739696958b-2ffa-418e-95b3-19f1941fa10c
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-01-15 | |||||
タイトル | ||||||
タイトル | Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki–Heck and Intramolecular Diels–Alder Reactions | |||||
言語 | en | |||||
著者 |
Watanabe, Shogo
× Watanabe, Shogo× Nishikawa, Toshio× Nakazaki, Atsuo |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-CsaX6tmA87bVW2gfdct6].” | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Steroids | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Chemical structure | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Hydrocarbons | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Precursors | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Stereoselectivity | |||||
抄録 | ||||||
内容記述 | Estrogenic and cardiotonic steroidal skeletons were concisely constructed via Mizoroki–Heck and intramolecular Diels–Alder (IMDA) reactions. Simple modification of the dienophile unsaturation of the IMDA precursor enabled representative AB-ring systems of both steroid classes to be accessed from the same intermediate. The diastereoselectivity of the IMDA reaction used to access the cardiotonic steroidal skeleton was found to be significantly enhanced by performing the reaction in water. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2020-09-20 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | ACS Publications | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/acs.orglett.9b02716 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1523-7060 | |||||
書誌情報 |
en : Organic Letters 巻 21, 号 18, p. 7410-7414, 発行日 2019-09-20 |
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著者版フラグ | ||||||
値 | author |