{"created":"2021-03-01T06:37:07.602738+00:00","id":28986,"links":{},"metadata":{"_buckets":{"deposit":"6d9f0342-4ba3-499d-b91d-fd61f5b33712"},"_deposit":{"id":"28986","owners":[],"pid":{"revision_id":0,"type":"depid","value":"28986"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00028986","sets":["643:666:667"]},"author_link":["95200","95201","95202"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-09-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"18","bibliographicPageEnd":"7414","bibliographicPageStart":"7410","bibliographicVolumeNumber":"21","bibliographic_titles":[{"bibliographic_title":"Organic Letters","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Estrogenic and cardiotonic steroidal skeletons were concisely constructed via Mizoroki–Heck and intramolecular Diels–Alder (IMDA) reactions. Simple modification of the dienophile unsaturation of the IMDA precursor enabled representative AB-ring systems of both steroid classes to be accessed from the same intermediate. The diastereoselectivity of the IMDA reaction used to access the cardiotonic steroidal skeleton was found to be significantly enhanced by performing the reaction in water.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2020-09-20","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.orglett.9b02716","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-CsaX6tmA87bVW2gfdct6].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"1523-7060","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Watanabe, Shogo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95200","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishikawa, Toshio","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95201","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakazaki, Atsuo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95202","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-20"}],"displaytype":"detail","filename":"revised_main_text.pdf","filesize":[{"value":"839.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"revised_main_text","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/28986/files/revised_main_text.pdf"},"version_id":"a1de6509-ef45-4fbd-873c-d4608f3fa84a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Steroids","subitem_subject_scheme":"Other"},{"subitem_subject":"Chemical structure","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydrocarbons","subitem_subject_scheme":"Other"},{"subitem_subject":"Precursors","subitem_subject_scheme":"Other"},{"subitem_subject":"Stereoselectivity","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki–Heck and Intramolecular Diels–Alder Reactions","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki–Heck and Intramolecular Diels–Alder Reactions","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["667"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-01-15"},"publish_date":"2020-01-15","publish_status":"0","recid":"28986","relation_version_is_last":true,"title":["Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki–Heck and Intramolecular Diels–Alder Reactions"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T05:11:09.028272+00:00"}