{"created":"2021-03-01T06:37:07.735088+00:00","id":28988,"links":{},"metadata":{"_buckets":{"deposit":"414c052b-e1d1-4df3-9240-a4f393ceb369"},"_deposit":{"id":"28988","owners":[],"pid":{"revision_id":0,"type":"depid","value":"28988"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00028988","sets":["336:695:696"]},"author_link":["95206","95207","95208","95209","95210","95211","95212","95213"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-10-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"19","bibliographicPageEnd":"4714","bibliographicPageStart":"4709","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"ChemCatChem","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A new type of high‐pressure reactor based on liquid‐flow pressurisation using a HPLC pump has been developed. This high‐pressure reactor allows the easy and safe performance of reactions with gaseous alkanes under high‐pressures up to 10 MPa (100 atm), without the need for high‐pressure gas cylinders. The amount of substrate gas required for a single reaction is very small compared with reactions using a conventional autoclave, which, when using expensive substrate gasses, such as 13C‐labelled ethane, becomes critical. Employing this high‐pressure reactor in conjunction with cytochrome P450BM3 and the assistance of decoy molecules, the direct hydroxylation of gaseous alkanes was drastically improved. At 5 MPa the TOF of propane hydroxylation increased 10‐fold, reaching 2200 min^−1. Hydroxylation of ethane was also substantially accelerated at 5 MPa, reaching a TOF of 28 min^−1.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2020-10-07","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/cctc.201901323","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [S. Ariyasu, Y. Kodama, C. Kasai, Z. Cong, J. K. Stanfield, Y. Aiba, Y. Watanabe, O. Shoji, ChemCatChem 2019, 11, 4709.], which has been published in final form at [https://doi.org/10.1002/cctc.201901323]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"1867-3880","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ariyasu, Shinya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95206","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kodama, Yusaku","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95207","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kasai, Chie","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95208","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Cong, Zhiqi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95209","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Stanfield, Joshua Kyle","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95210","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Aiba, Yuichiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95211","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Watanabe, Yoshihito","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95212","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shoji, Osami","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95213","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-10-07"}],"displaytype":"detail","filename":"Manuscript_of_alkane_hydroxylation_byBM3_under_high_pressure_20190715.pdf","filesize":[{"value":"662.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Manuscript_of_alkane_hydroxylation_byBM3_under_high_pressure_20190715","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/28988/files/Manuscript_of_alkane_hydroxylation_byBM3_under_high_pressure_20190715.pdf"},"version_id":"c07b128f-b4cb-4b49-b690-e75ecb5cc5c8"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"high pressure","subitem_subject_scheme":"Other"},{"subitem_subject":"cytochrome P450","subitem_subject_scheme":"Other"},{"subitem_subject":"hydroxylation","subitem_subject_scheme":"Other"},{"subitem_subject":"ethane","subitem_subject_scheme":"Other"},{"subitem_subject":"propane","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Development of a High‐Pressure Reactor Based on Liquid‐Flow Pressurisation to Facilitate Enzymatic Hydroxylation of Gaseous Alkanes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Development of a High‐Pressure Reactor Based on Liquid‐Flow Pressurisation to Facilitate Enzymatic Hydroxylation of Gaseous Alkanes","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-01-15"},"publish_date":"2020-01-15","publish_status":"0","recid":"28988","relation_version_is_last":true,"title":["Development of a High‐Pressure Reactor Based on Liquid‐Flow Pressurisation to Facilitate Enzymatic Hydroxylation of Gaseous Alkanes"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:21:43.342621+00:00"}