{"created":"2021-03-01T06:37:08.669213+00:00","id":29002,"links":{},"metadata":{"_buckets":{"deposit":"789b2ef0-83e4-4296-b203-0767b009ea02"},"_deposit":{"id":"29002","owners":[],"pid":{"revision_id":0,"type":"depid","value":"29002"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00029002","sets":["1903:1904:1905"]},"author_link":["95266","95267","95268","95269"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-10-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"19","bibliographicPageEnd":"12519","bibliographicPageStart":"12508","bibliographicVolumeNumber":"84","bibliographic_titles":[{"bibliographic_title":"The Journal of Organic Chemistry","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We established a method for installing a methyl group at the β-position of a butenolide ring. The methylated position is located at the congested ring juncture of a 5,6,5-tricyclic lactone, which is common to neurotrophic seco-prezizaane-type sesquiterpenes. The samarium(II)-mediated conjugate addition of the halomethylsilyl ethers tethered to the proximal hydroxy groups efficiently formed the desired C–C bond. Subsequent fluoride-free Tamao oxidation and Barton–McCombie deoxygenation converted the resultant cyclic silyl ether into the corresponding methyl group.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2020-10-04","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.joc.9b02017","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Organic Chemistry], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-i5vuyRS94wFJb4GXufGB].”"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0022-3263","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kawamura, Tomoyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95266","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Moriya, Hirokazu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95267","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shibuya, Masatoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95268","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamamoto, Yoshihiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95269","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-10-04"}],"displaytype":"detail","filename":"Manuscript.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Manuscript","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/29002/files/Manuscript.pdf"},"version_id":"6dbe11c9-1d6a-4495-a911-d16a9b57d9ab"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Diastereoselective Methylation at the Congested β-Position of a Butenolide Ring: Studies toward the Synthesis of seco-Prezizaane-Type Sesquiterpenes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Diastereoselective Methylation at the Congested β-Position of a Butenolide Ring: Studies toward the Synthesis of seco-Prezizaane-Type Sesquiterpenes","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1905"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-01-16"},"publish_date":"2020-01-16","publish_status":"0","recid":"29002","relation_version_is_last":true,"title":["Diastereoselective Methylation at the Congested β-Position of a Butenolide Ring: Studies toward the Synthesis of seco-Prezizaane-Type Sesquiterpenes"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T05:03:45.154850+00:00"}