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  1. B100 理学部/理学研究科
  2. B100a 雑誌掲載論文
  3. 学術雑誌

Transition Metal Complexes and Radical Anion Salts of 1,10-Phenanthroline Derivatives Annulated with a 1,2,5-Tiadiazole and 1,2,5-Tiadiazole 1,1-Dioxide Moiety: Multidimensional Crystal Structures and Various Magnetic Properties

http://hdl.handle.net/2237/00031411
http://hdl.handle.net/2237/00031411
5ae2d26e-3069-4c00-ac7e-b09d471142a2
名前 / ファイル ライセンス アクション
molecules-19-00609.pdf molecules-19-00609 (1.3 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-01-29
タイトル
タイトル Transition Metal Complexes and Radical Anion Salts of 1,10-Phenanthroline Derivatives Annulated with a 1,2,5-Tiadiazole and 1,2,5-Tiadiazole 1,1-Dioxide Moiety: Multidimensional Crystal Structures and Various Magnetic Properties
言語 en
著者 Shuku, Yoshiaki

× Shuku, Yoshiaki

WEKO 95810

en Shuku, Yoshiaki

Search repository
Awaga, Kunio

× Awaga, Kunio

WEKO 95811

en Awaga, Kunio

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 © 2014 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
キーワード
主題Scheme Other
主題 spin-crossover complexes
キーワード
主題Scheme Other
主題 intermolecular interactions
キーワード
主題Scheme Other
主題 electron acceptors
キーワード
主題Scheme Other
主題 radical anion salts
抄録
内容記述 Advances in the molecular variety and the elucidation of the physical properties of 1,10-phenanthroline annulated with 1,2,5-thiadiazole and 1,2,5-thiadiazole 1,1-dioxide moieties have been achieved, and are described herein. A 1,2,5-thiadiazole compound, [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline (tdap), was used as a ligand to create multidimensional network structures based on S•••S and S•••N intermolecular interactions. A 1,2,5-thiadiazole 1,1-dioxide compound, [1,2,5] thiadiazolo[3,4-f][1,10]phenanthroline, 1,1-dioxide (tdapO2), was designed to create a stable radical anion, as well as good network structures. Single crystal X-ray structure analyses revealed that transition metal complexes of tdap, and radical anion salts of tdapO2 formed multidimensional network structures, as expected. Two kinds of tdap iron complexes, namely [Fe(tdap)2(NCS)2] and [Fe(tdap)2(NCS)2]•MeCN exhibited spin crossover transitions, and their transition temperatures showed a difference of 150 K, despite their similar molecular structures. Magnetic measurements for the tdapO2 radical anion salts revealed that the magnetic coupling constants between neighboring radical species vary from strongly antiferromagnetic (J = −320 K) to ferromagnetic (J = 24 K), reflecting the differences in their π overlap motifs.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 MDPI
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.3390/molecules19010609
ISSN(Online)
収録物識別子タイプ EISSN
収録物識別子 1420-3049
書誌情報 en : Molecules

巻 19, 号 1, p. 609-640, 発行日 2014-01-07
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