{"_buckets": {"deposit": "41786cf2-242c-4e0d-a359-49eb8c064df8"}, "_deposit": {"id": "29224", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "29224"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00029224"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-01-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "640", "bibliographicPageStart": "609", "bibliographicVolumeNumber": "19", "bibliographic_titles": [{"bibliographic_title": "Molecules"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Advances in the molecular variety and the elucidation of the physical properties of 1,10-phenanthroline annulated with 1,2,5-thiadiazole and 1,2,5-thiadiazole 1,1-dioxide moieties have been achieved, and are described herein. A 1,2,5-thiadiazole compound, [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline (tdap), was used as a ligand to create multidimensional network structures based on S\u2022\u2022\u2022S and S\u2022\u2022\u2022N intermolecular interactions. A 1,2,5-thiadiazole 1,1-dioxide compound, [1,2,5] thiadiazolo[3,4-f][1,10]phenanthroline, 1,1-dioxide (tdapO2), was designed to create a stable radical anion, as well as good network structures. Single crystal X-ray structure analyses revealed that transition metal complexes of tdap, and radical anion salts of tdapO2 formed multidimensional network structures, as expected. Two kinds of tdap iron complexes, namely [Fe(tdap)2(NCS)2] and [Fe(tdap)2(NCS)2]\u2022MeCN exhibited spin crossover transitions, and their transition temperatures showed a difference of 150 K, despite their similar molecular structures. Magnetic measurements for the tdapO2 radical anion salts revealed that the magnetic coupling constants between neighboring radical species vary from strongly antiferromagnetic (J = \u2212320 K) to ferromagnetic (J = 24 K), reflecting the differences in their \u03c0 overlap motifs.", "subitem_description_type": "Abstract"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "MDPI"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.3390/molecules19010609", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u00a9 2014 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/)."}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_62": {"attribute_name": "ISSN\uff08Online\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1420-3049", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shuku, Yoshiaki"}], "nameIdentifiers": [{"nameIdentifier": "95810", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Awaga, Kunio"}], "nameIdentifiers": [{"nameIdentifier": "95811", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-01-29"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "molecules-19-00609.pdf", "filesize": [{"value": "1.3 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1300000.0, "url": {"label": "molecules-19-00609", "url": "https://nagoya.repo.nii.ac.jp/record/29224/files/molecules-19-00609.pdf"}, "version_id": "f6a71fcc-cddf-4f32-903b-09747ff2057f"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "spin-crossover complexes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "intermolecular interactions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "electron acceptors", "subitem_subject_scheme": "Other"}, {"subitem_subject": "radical anion salts", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Transition Metal Complexes and Radical Anion Salts of  1,10-Phenanthroline Derivatives Annulated with a  1,2,5-Tiadiazole and 1,2,5-Tiadiazole 1,1-Dioxide Moiety: Multidimensional Crystal Structures and Various  Magnetic Properties", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Transition Metal Complexes and Radical Anion Salts of  1,10-Phenanthroline Derivatives Annulated with a  1,2,5-Tiadiazole and 1,2,5-Tiadiazole 1,1-Dioxide Moiety: Multidimensional Crystal Structures and Various  Magnetic Properties"}]}, "item_type_id": "10", "owner": "1", "path": ["336/695/696"], "permalink_uri": "http://hdl.handle.net/2237/00031411", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2020-01-29"}, "publish_date": "2020-01-29", "publish_status": "0", "recid": "29224", "relation": {}, "relation_version_is_last": true, "title": ["Transition Metal Complexes and Radical Anion Salts of  1,10-Phenanthroline Derivatives Annulated with a  1,2,5-Tiadiazole and 1,2,5-Tiadiazole 1,1-Dioxide Moiety: Multidimensional Crystal Structures and Various  Magnetic Properties"], "weko_shared_id": null}