{"created":"2021-03-01T06:37:23.472911+00:00","id":29224,"links":{},"metadata":{"_buckets":{"deposit":"41786cf2-242c-4e0d-a359-49eb8c064df8"},"_deposit":{"id":"29224","owners":[],"pid":{"revision_id":0,"type":"depid","value":"29224"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00029224","sets":["336:695:696"]},"author_link":["95810","95811"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-01-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"640","bibliographicPageStart":"609","bibliographicVolumeNumber":"19","bibliographic_titles":[{"bibliographic_title":"Molecules","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Advances in the molecular variety and the elucidation of the physical properties of 1,10-phenanthroline annulated with 1,2,5-thiadiazole and 1,2,5-thiadiazole 1,1-dioxide moieties have been achieved, and are described herein. A 1,2,5-thiadiazole compound, [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline (tdap), was used as a ligand to create multidimensional network structures based on S•••S and S•••N intermolecular interactions. A 1,2,5-thiadiazole 1,1-dioxide compound, [1,2,5] thiadiazolo[3,4-f][1,10]phenanthroline, 1,1-dioxide (tdapO2), was designed to create a stable radical anion, as well as good network structures. Single crystal X-ray structure analyses revealed that transition metal complexes of tdap, and radical anion salts of tdapO2 formed multidimensional network structures, as expected. Two kinds of tdap iron complexes, namely [Fe(tdap)2(NCS)2] and [Fe(tdap)2(NCS)2]•MeCN exhibited spin crossover transitions, and their transition temperatures showed a difference of 150 K, despite their similar molecular structures. Magnetic measurements for the tdapO2 radical anion salts revealed that the magnetic coupling constants between neighboring radical species vary from strongly antiferromagnetic (J = −320 K) to ferromagnetic (J = 24 K), reflecting the differences in their π overlap motifs.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"MDPI","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.3390/molecules19010609","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2014 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_10_source_id_62":{"attribute_name":"ISSN（Online）","attribute_value_mlt":[{"subitem_source_identifier":"1420-3049","subitem_source_identifier_type":"EISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shuku, Yoshiaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95810","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Awaga, Kunio","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"95811","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-29"}],"displaytype":"detail","filename":"molecules-19-00609.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"molecules-19-00609","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/29224/files/molecules-19-00609.pdf"},"version_id":"f6a71fcc-cddf-4f32-903b-09747ff2057f"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"spin-crossover complexes","subitem_subject_scheme":"Other"},{"subitem_subject":"intermolecular interactions","subitem_subject_scheme":"Other"},{"subitem_subject":"electron acceptors","subitem_subject_scheme":"Other"},{"subitem_subject":"radical anion salts","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Transition Metal Complexes and Radical Anion Salts of  1,10-Phenanthroline Derivatives Annulated with a  1,2,5-Tiadiazole and 1,2,5-Tiadiazole 1,1-Dioxide Moiety: Multidimensional Crystal Structures and Various  Magnetic Properties","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Transition Metal Complexes and Radical Anion Salts of  1,10-Phenanthroline Derivatives Annulated with a  1,2,5-Tiadiazole and 1,2,5-Tiadiazole 1,1-Dioxide Moiety: Multidimensional Crystal Structures and Various  Magnetic Properties","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-01-29"},"publish_date":"2020-01-29","publish_status":"0","recid":"29224","relation_version_is_last":true,"title":["Transition Metal Complexes and Radical Anion Salts of  1,10-Phenanthroline Derivatives Annulated with a  1,2,5-Tiadiazole and 1,2,5-Tiadiazole 1,1-Dioxide Moiety: Multidimensional Crystal Structures and Various  Magnetic Properties"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:22:21.471086+00:00"}