{"_buckets": {"deposit": "cf85db18-2ffc-4601-88d1-28a379b07dff"}, "_deposit": {"id": "29315", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "29315"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00029315", "sets": ["1941"]}, "author_link": ["95991", "95992", "95993", "95994", "95995", "95996", "95997", "95998"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2019-10-22", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "20", "bibliographicPageEnd": "8439", "bibliographicPageStart": "8432", "bibliographicVolumeNumber": "31", "bibliographic_titles": [{"bibliographic_title": "Chemistry of Materials", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Cyclo[60]fullerenes are widely used in many applications including photovoltaic devices owing to their high electron affinity and mobility for an organic molecule. However, their synthesis has been limited to certain derivatives with low yields. In this work, a fullerene-cation-mediated synthesis, accessing a new class of five-membered carbon ring cyclo[60]fullerenes with high yields of up to 93% is showcased. This method utilizes aryl[60]fullerene cations, ArC60+, as intermediates, which are generated in situ by heating the aryl[60]fullerenyl dimers in the presence of CuBr2. In addition, five-membered carbon ring cyclo[60]fullerenes display excellent device applicability when they are used in perovskite solar cells as over-coating layers of electron-transporting layers. A power conversion efficiency of 20.7% is achieved owing to the favorable energy alignment, optimized substrate design, and electrochemical stability of the five-membered carbon ring fullerenes.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開：2020-10-22", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.chemmater.9b02468", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Chemistry of Materials], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-qahTybN5KH4HTNI9HsnR].”", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN（print）", "attribute_value_mlt": [{"subitem_source_identifier": "0897-4756", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Lin, Hao-Sheng", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "95991", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Jeon, Il", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "95992", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Chen, Yingqian", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "95993", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yang, Xiao-Yu", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "95994", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakagawa, Takafumi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "95995", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maruyama, Shigeo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "95996", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Manzhos, Sergei", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "95997", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsuo, Yutaka", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "95998", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-10-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "FIF PSC ChemMater final matsuo.pdf", "filesize": [{"value": "1.8 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1800000.0, "url": {"label": "FIF PSC ChemMater final matsuo", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/29315/files/FIF PSC ChemMater final matsuo.pdf"}, "version_id": "e626fdf8-e3c6-4474-a1b0-285b91a6b458"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Highly Selective and Scalable Fullerene-Cation-Mediated Synthesis Accessing Cyclo[60]fullerenes with Five-Membered Carbon Ring and Their Application to Perovskite Solar Cells", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Highly Selective and Scalable Fullerene-Cation-Mediated Synthesis Accessing Cyclo[60]fullerenes with Five-Membered Carbon Ring and Their Application to Perovskite Solar Cells", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["1941"], "permalink_uri": "http://hdl.handle.net/2237/00031502", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2020-02-13"}, "publish_date": "2020-02-13", "publish_status": "0", "recid": "29315", "relation": {}, "relation_version_is_last": true, "title": ["Highly Selective and Scalable Fullerene-Cation-Mediated Synthesis Accessing Cyclo[60]fullerenes with Five-Membered Carbon Ring and Their Application to Perovskite Solar Cells"], "weko_shared_id": -1}