{"created":"2021-03-01T06:37:29.771780+00:00","id":29316,"links":{},"metadata":{"_buckets":{"deposit":"34130c47-8dad-4318-8d19-ebc4f9c76aa3"},"_deposit":{"id":"29316","owners":[],"pid":{"revision_id":0,"type":"depid","value":"29316"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00029316","sets":["1939:1940:1941"]},"author_link":["96000","96001","96002","96003","96004","96005","96006","96007","96008","96009","96010","96011","96012","96013"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-10-23","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"42","bibliographicPageEnd":"16558","bibliographicPageStart":"16553","bibliographicVolumeNumber":"141","bibliographic_titles":[{"bibliographic_title":"Journal of the American Chemical Society","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"High efficiency perovskite solar cells have underpinned the rapid growth of the field. However, their low device stability limits further advancement. Hygroscopic lithium bis(trifluoromethanesulfonyl)imide (Li^+TFSI^–) and metal electrode are the main causes of the device instability. In this work, the redox reaction between lithium-ion endohedral fullerenes and 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobi-fluorene (spiro-MeOTAD) was controlled to optimize the amount of oxidized spiro-MeOTAD and antioxidizing neutral endohedral fullerenes. Application of this mixture to metal-free carbon nanotube (CNT)-laminated perovskite solar cells resulted in 17.2% efficiency with a stability time of more than 1100 h under severe conditions (temperature = 60 °C, humidity = 70%). Such high performance is attributed to the uninhibited charge flow, no metal-ion migration, and the enhanced antioxidizing activity of the devices.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2020-10-23","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/jacs.9b06418","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-xJzrWDW3Dsxtz4c5gPGA].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0002-7863","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Jeon, Il","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96000","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shawky, Ahmed","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96001","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lin, Hao-Sheng","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96002","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Seo, Seungju","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96003","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okada, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96004","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lee, Jin-Wook","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96005","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Pal, Amrita","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96006","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tan, Shaun","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96007","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Anisimov, Anton","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96008","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kauppinen, Esko I.","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96009","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yang, Yang","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96010","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Manzhos, Sergei","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96011","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Maruyama, Shigeo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96012","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsuo, Yutaka","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"96013","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-10-23"}],"displaytype":"detail","filename":"LiC60TFSI CNT MS JACS revised 2.pdf","filesize":[{"value":"4.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"LiC60TFSI CNT MS JACS revised 2","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/29316/files/LiC60TFSI CNT MS JACS revised 2.pdf"},"version_id":"f941dbb9-2cd2-403a-bb41-48938eac4f31"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Endohedral Fullerene","subitem_subject_scheme":"Other"},{"subitem_subject":"Metallofullerene","subitem_subject_scheme":"Other"},{"subitem_subject":"Carbon Nanotube","subitem_subject_scheme":"Other"},{"subitem_subject":"Perovskite Solar Cells","subitem_subject_scheme":"Other"},{"subitem_subject":"Stability of Solar Cells","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1941"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-02-13"},"publish_date":"2020-02-13","publish_status":"0","recid":"29316","relation_version_is_last":true,"title":["Controlled Redox of Lithium-Ion Endohedral Fullerene for Efficient and Stable Metal Electrode-Free Perovskite Solar Cells"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:29:11.165423+00:00"}