{"_buckets": {"deposit": "c390b286-b88f-42bf-b5da-6cfa9a6bde42"}, "_deposit": {"id": "29318", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "29318"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00029318"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-02-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "3", "bibliographicPageEnd": "955", "bibliographicPageStart": "950", "bibliographicVolumeNumber": "22", "bibliographic_titles": [{"bibliographic_title": "Organic Letters"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Deaminative functionalization of aliphatic primary amines has great synthetic utility. Herein, we describe a Ni-catalyzed reductive deaminative cross-electrophile coupling reaction between Katritzky salts and aromatic amides. This work provides examples of the synthesis of various ketones from alkylpyridinium salts, including both primary and secondary alkylamines. Given its mild reaction conditions and high functional group tolerance, this cross-coupling strategy is expected to be useful for late-stage functionalization of complex compounds.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021/2/7", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.orglett.9b04497", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-XdzeDgJjUS52CekJXgNP].\u201d"}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1523-7060", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yu, Chu-Guo"}], "nameIdentifiers": [{"nameIdentifier": "96017", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsuo, Yutaka"}], "nameIdentifiers": [{"nameIdentifier": "96018", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-02-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Ni-catalyzed Acylation manuscript-final-1.07b.pdf", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "Ni-catalyzed Acylation manuscript-final-1.07b", "url": "https://nagoya.repo.nii.ac.jp/record/29318/files/Ni-catalyzed Acylation manuscript-final-1.07b.pdf"}, "version_id": "f8d068a3-2e4e-46b5-873e-a8b4e3d52203"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Salts", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Amides", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Alkyls", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Amines", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Cross coupling reaction", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Nickel-Catalyzed Deaminative Acylation of Activated Aliphatic Amines with Aromatic Amides via C\u2013N Bond Activation", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Nickel-Catalyzed Deaminative Acylation of Activated Aliphatic Amines with Aromatic Amides via C\u2013N Bond Activation"}]}, "item_type_id": "10", "owner": "1", "path": ["1939/1940/1941"], "permalink_uri": "http://hdl.handle.net/2237/00031505", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2020-02-13"}, "publish_date": "2020-02-13", "publish_status": "0", "recid": "29318", "relation": {}, "relation_version_is_last": true, "title": ["Nickel-Catalyzed Deaminative Acylation of Activated Aliphatic Amines with Aromatic Amides via C\u2013N Bond Activation"], "weko_shared_id": null}