{"created":"2021-03-01T06:38:24.907299+00:00","id":30135,"links":{},"metadata":{"_buckets":{"deposit":"a241dce6-6e8e-4df0-be27-e14a17469ebd"},"_deposit":{"id":"30135","owners":[],"pid":{"revision_id":0,"type":"depid","value":"30135"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00030135","sets":["320:321:322"]},"author_link":["99471","99472","99473","99474"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"01n03","bibliographicPageEnd":"89","bibliographicPageStart":"84","bibliographicVolumeNumber":"24","bibliographic_titles":[{"bibliographic_title":"Journal of Porphyrins and Phthalocyanines","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have successfully prepared 5-aza-15-thiaporphyrin through nucleophilic sulfination of nitrogen-bridged dibromobisdipyrrin with sodium sulfide. X-ray diffraction analysis elucidated its structure in the solid state: two dipyrrin subunits were roughly coplanar around the sp^2-hybridized meso-nitrogen. In contrast, they adopted a folded conformation around the meso-sulfur atom. Due to its relatively distorted structure, 5-aza-15-thiaporphyrin shows weak antiaromaticity in the magnetic criteria. The sulfur atom was oxidized with m-chloroperbenzoic acid to provide 5-aza-15-thiaporphyrin S-dioxide in good yield. While 5-aza-15-thiaporphyrin was non-emissive, its S-dioxide exhibited fluorescence in solution.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021/03/01","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"World Scientific","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1142/S108842461950069X","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Electronic version of an article published as [Journal of Porphyrins and Phthalocyanines. v.24, n.01n03, 2020, p.84-89] [http://doi.org/10.1142/S108842461950069X] © [copyright World Scientific Publishing Company] [https://www.worldscientific.com/worldscinet/jpp]","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"1088-4246","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamashita, Daisuke","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99471","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Omori, Hiroto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99472","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukui, Norihito","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99473","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shinokubo, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99474","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-03-01"}],"displaytype":"detail","filename":"shinokubo_man-revised.pdf","filesize":[{"value":"3.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"shinokubo_man-revised","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/30135/files/shinokubo_man-revised.pdf"},"version_id":"18f2d381-1198-4662-8a9e-7baaca10eb2b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"5-aza-15-thiaporphyrin","subitem_subject_scheme":"Other"},{"subitem_subject":"antiaromaticity","subitem_subject_scheme":"Other"},{"subitem_subject":"heteroporphyrinoids","subitem_subject_scheme":"Other"},{"subitem_subject":"sulfide","subitem_subject_scheme":"Other"},{"subitem_subject":"sulfone","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and properties of 5-aza-15-thiaporphyrins","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis and properties of 5-aza-15-thiaporphyrins","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-06-09"},"publish_date":"2020-06-09","publish_status":"0","recid":"30135","relation_version_is_last":true,"title":["Synthesis and properties of 5-aza-15-thiaporphyrins"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:22:42.849972+00:00"}