{"created":"2021-03-01T06:38:25.253850+00:00","id":30140,"links":{},"metadata":{"_buckets":{"deposit":"0d805637-c4b3-425f-b11a-9902f6452286"},"_deposit":{"id":"30140","owners":[],"pid":{"revision_id":0,"type":"depid","value":"30140"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00030140","sets":["1903:1904:1905"]},"author_link":["99491","99492","99493","99494"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-04-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"15","bibliographicPageEnd":"6257","bibliographicPageStart":"6253","bibliographicVolumeNumber":"59","bibliographic_titles":[{"bibliographic_title":"Angewandte Chemie International Edition","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A total synthesis of tetrodotoxin was accomplished. A Diels–Alder reaction between a known enone and a siloxy diene gave a tricyclic product, the steric bias of which was used to construct the remaining stereogenic centers. A nitrogen atom was introduced either by a four‐step sequence involving a Curtius rearrangement, or a three‐step sequence featuring a newly developed transformation of a terminal alkyne into a nitrile. Introduction of the guanidine moiety followed by the formation of the heterocyclic system by cascade reactions led to tetrodotoxin.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021-04-06","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201916611","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [K. Murakami, T. Toma, T. Fukuyama, S. Yokoshima, Angew. Chem. Int. Ed. 2020 , 59 , 6253.], which has been published in final form at [https://doi.org/10.1002/anie.201916611]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions."}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"1433-7851","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Murakami, Keigo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99491","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Toma, Tatsuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99492","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukuyama, Tohru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99493","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yokoshima, Satoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99494","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-04-06"}],"displaytype":"detail","filename":"20200122_ttx_ACIE_revision_tc.pdf","filesize":[{"value":"759.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"20200122_ttx_ACIE_revision_tc","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/30140/files/20200122_ttx_ACIE_revision_tc.pdf"},"version_id":"8c43f921-60ac-4bbc-a476-29c7af46ad4f"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Total Synthesis of Tetrodotoxin","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Total Synthesis of Tetrodotoxin","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1905"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-06-10"},"publish_date":"2020-06-10","publish_status":"0","recid":"30140","relation_version_is_last":true,"title":["Total Synthesis of Tetrodotoxin"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:23:09.480007+00:00"}