ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

{"_buckets": {"deposit": "cd12c515-8fac-4b2b-a0f2-e5b83d8e66e5"}, "_deposit": {"id": "30143", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30143"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030143", "sets": ["322"]}, "author_link": ["99504", "99505", "99506"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-02-17", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "10", "bibliographicPageEnd": "2177", "bibliographicPageStart": "2174", "bibliographicVolumeNumber": "26", "bibliographic_titles": [{"bibliographic_title": "Chemistry–A European Journal", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The reactivity of dialkylalumanyl anion (1) towards naphthalene, anthracene, diphenylacetylene, and (E)/(Z)‐stilbenes was investigated. The compound 1 reacts with naphthalene and anthracene through (1+4) cyclization, giving Al‐containing norbornadiene derivatives. In the reaction of 1 with diphenylacetylene and (E)/(Z)‐stilbenes, (1+2) cyclization proceeded to form Al‐C‐C three‐membered rings. Cyclization toward (E)‐ or (Z)‐stilbenes solely gave a trans ‐cycloadduct. DFT calculations revealed that the cycloaddition of 1 with (Z)‐stilbene proceeds via a single transition state with a carbanion character, which results in the selectivity towards the trans ‐cycloadduct.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開:2021-02-17", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/chem.201905830", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: [K. Sugita, R. Nakano, M. Yamashita, Chem. Eur. J. 2020 , 26 , 2174.], which has been published in final form at [https://doi.org/10.1002/chem.201905830]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN(print)", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Sugita, Kengo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "99504", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakano, Ryo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "99505", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamashita, Makoto", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "99506", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-02-17"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Text20191224.pdf", "filesize": [{"value": "619.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 619700.0, "url": {"label": "Text20191224", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/30143/files/Text20191224.pdf"}, "version_id": "be053f35-1b88-4afd-be3d-ccb20ce27b28"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "alumanyl anions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "aluminum", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cycloaddition", "subitem_subject_scheme": "Other"}, {"subitem_subject": "density functional calculations", "subitem_subject_scheme": "Other"}, {"subitem_subject": "low oxidation states", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/00032329", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2020-06-10"}, "publish_date": "2020-06-10", "publish_status": "0", "recid": "30143", "relation": {}, "relation_version_is_last": true, "title": ["Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes"], "weko_shared_id": -1}
  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes

http://hdl.handle.net/2237/00032329
http://hdl.handle.net/2237/00032329
969520be-83c4-4351-adec-0ab4a566694d
名前 / ファイル ライセンス アクション
Text20191224.pdf Text20191224 (619.7 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-06-10
タイトル
タイトル Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes
言語 en
著者 Sugita, Kengo

× Sugita, Kengo

WEKO 99504

en Sugita, Kengo

Search repository
Nakano, Ryo

× Nakano, Ryo

WEKO 99505

en Nakano, Ryo

Search repository
Yamashita, Makoto

× Yamashita, Makoto

WEKO 99506

en Yamashita, Makoto

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [K. Sugita, R. Nakano, M. Yamashita, Chem. Eur. J. 2020 , 26 , 2174.], which has been published in final form at [https://doi.org/10.1002/chem.201905830]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
キーワード
主題Scheme Other
主題 alumanyl anions
キーワード
主題Scheme Other
主題 aluminum
キーワード
主題Scheme Other
主題 cycloaddition
キーワード
主題Scheme Other
主題 density functional calculations
キーワード
主題Scheme Other
主題 low oxidation states
抄録
内容記述 The reactivity of dialkylalumanyl anion (1) towards naphthalene, anthracene, diphenylacetylene, and (E)/(Z)‐stilbenes was investigated. The compound 1 reacts with naphthalene and anthracene through (1+4) cyclization, giving Al‐containing norbornadiene derivatives. In the reaction of 1 with diphenylacetylene and (E)/(Z)‐stilbenes, (1+2) cyclization proceeded to form Al‐C‐C three‐membered rings. Cyclization toward (E)‐ or (Z)‐stilbenes solely gave a trans ‐cycloadduct. DFT calculations revealed that the cycloaddition of 1 with (Z)‐stilbene proceeds via a single transition state with a carbanion character, which results in the selectivity towards the trans ‐cycloadduct.
言語 en
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2021-02-17
言語 ja
内容記述タイプ Other
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/chem.201905830
ISSN(print)
収録物識別子タイプ PISSN
収録物識別子 0947-6539
書誌情報 en : Chemistry–A European Journal

巻 26, 号 10, p. 2174-2177, 発行日 2020-02-17
著者版フラグ
値 author
戻る
0
views
See details
Views

Versions

Ver.1 2021-03-01 09:06:30.517322
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3