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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes

http://hdl.handle.net/2237/00032329
969520be-83c4-4351-adec-0ab4a566694d
名前 / ファイル ライセンス アクション
Text20191224.pdf Text20191224 (619.7 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-06-10
タイトル
タイトル Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes
著者 Sugita, Kengo

× Sugita, Kengo

WEKO 99504

Sugita, Kengo

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Nakano, Ryo

× Nakano, Ryo

WEKO 99505

Nakano, Ryo

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Yamashita, Makoto

× Yamashita, Makoto

WEKO 99506

Yamashita, Makoto

Search repository
権利
権利情報 "This is the peer reviewed version of the following article: [K. Sugita, R. Nakano, M. Yamashita, Chem. Eur. J. 2020 , 26 , 2174.], which has been published in final form at [https://doi.org/10.1002/chem.201905830]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions."
キーワード
主題Scheme Other
主題 alumanyl anions
キーワード
主題Scheme Other
主題 aluminum
キーワード
主題Scheme Other
主題 cycloaddition
キーワード
主題Scheme Other
主題 density functional calculations
キーワード
主題Scheme Other
主題 low oxidation states
抄録
内容記述 The reactivity of dialkylalumanyl anion (1) towards naphthalene, anthracene, diphenylacetylene, and (E)/(Z)‐stilbenes was investigated. The compound 1 reacts with naphthalene and anthracene through (1+4) cyclization, giving Al‐containing norbornadiene derivatives. In the reaction of 1 with diphenylacetylene and (E)/(Z)‐stilbenes, (1+2) cyclization proceeded to form Al‐C‐C three‐membered rings. Cyclization toward (E)‐ or (Z)‐stilbenes solely gave a trans ‐cycloadduct. DFT calculations revealed that the cycloaddition of 1 with (Z)‐stilbene proceeds via a single transition state with a carbanion character, which results in the selectivity towards the trans ‐cycloadduct.
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2021-02-17
内容記述タイプ Other
出版者
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/chem.201905830
ISSN(print)
収録物識別子タイプ ISSN
収録物識別子 0947-6539
書誌情報 Chemistry–A European Journal

巻 26, 号 10, p. 2174-2177, 発行日 2020-02-17
著者版フラグ
値 author
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