{"_buckets": {"deposit": "cd12c515-8fac-4b2b-a0f2-e5b83d8e66e5"}, "_deposit": {"id": "30143", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30143"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030143"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-02-17", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "10", "bibliographicPageEnd": "2177", "bibliographicPageStart": "2174", "bibliographicVolumeNumber": "26", "bibliographic_titles": [{"bibliographic_title": "Chemistry\u2013A European Journal"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The reactivity of dialkylalumanyl anion (1) towards naphthalene, anthracene, diphenylacetylene, and (E)/(Z)\u2010stilbenes was investigated. The compound\u20051 reacts with naphthalene and anthracene through (1+4) cyclization, giving Al\u2010containing norbornadiene derivatives. In the reaction of 1 with diphenylacetylene and (E)/(Z)\u2010stilbenes, (1+2) cyclization proceeded to form Al\u2010C\u2010C three\u2010membered rings. Cyclization toward (E)\u2010 or (Z)\u2010stilbenes solely gave a trans \u2010cycloadduct. DFT calculations revealed that the cycloaddition of 1 with (Z)\u2010stilbene proceeds via a single transition state with a carbanion character, which results in the selectivity towards the trans \u2010cycloadduct.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021-02-17", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/chem.201905830", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [K. Sugita, R. Nakano, M. Yamashita, Chem. Eur. J. 2020 , 26 , 2174.], which has been published in final form at [https://doi.org/10.1002/chem.201905830]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Sugita, Kengo"}], "nameIdentifiers": [{"nameIdentifier": "99504", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakano, Ryo"}], "nameIdentifiers": [{"nameIdentifier": "99505", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamashita, Makoto"}], "nameIdentifiers": [{"nameIdentifier": "99506", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-02-17"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Text20191224.pdf", "filesize": [{"value": "619.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 619700.0, "url": {"label": "Text20191224", "url": "https://nagoya.repo.nii.ac.jp/record/30143/files/Text20191224.pdf"}, "version_id": "be053f35-1b88-4afd-be3d-ccb20ce27b28"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "alumanyl anions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "aluminum", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cycloaddition", "subitem_subject_scheme": "Other"}, {"subitem_subject": "density functional calculations", "subitem_subject_scheme": "Other"}, {"subitem_subject": "low oxidation states", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00032329", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2020-06-10"}, "publish_date": "2020-06-10", "publish_status": "0", "recid": "30143", "relation": {}, "relation_version_is_last": true, "title": ["Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes"], "weko_shared_id": null}