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Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes
http://hdl.handle.net/2237/00032329
969520be-83c4-4351-adec-0ab4a566694d
名前 / ファイル | ライセンス | アクション | |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-06-10 | |||||
タイトル | ||||||
タイトル | Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes | |||||
著者 |
Sugita, Kengo
× Sugita, Kengo× Nakano, Ryo× Yamashita, Makoto |
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権利 | ||||||
権利情報 | "This is the peer reviewed version of the following article: [K. Sugita, R. Nakano, M. Yamashita, Chem. Eur. J. 2020 , 26 , 2174.], which has been published in final form at [https://doi.org/10.1002/chem.201905830]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions." | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | alumanyl anions | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | aluminum | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | cycloaddition | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | density functional calculations | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | low oxidation states | |||||
抄録 | ||||||
内容記述 | The reactivity of dialkylalumanyl anion (1) towards naphthalene, anthracene, diphenylacetylene, and (E)/(Z)‐stilbenes was investigated. The compound 1 reacts with naphthalene and anthracene through (1+4) cyclization, giving Al‐containing norbornadiene derivatives. In the reaction of 1 with diphenylacetylene and (E)/(Z)‐stilbenes, (1+2) cyclization proceeded to form Al‐C‐C three‐membered rings. Cyclization toward (E)‐ or (Z)‐stilbenes solely gave a trans ‐cycloadduct. DFT calculations revealed that the cycloaddition of 1 with (Z)‐stilbene proceeds via a single transition state with a carbanion character, which results in the selectivity towards the trans ‐cycloadduct. | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2021-02-17 | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
DOI | ||||||
関連識別子 | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/chem.201905830 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0947-6539 | |||||
書誌情報 |
Chemistry–A European Journal 巻 26, 号 10, p. 2174-2177, 発行日 2020-02-17 |
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著者版フラグ | ||||||
値 | author |