{"created":"2021-03-01T06:38:25.528310+00:00","id":30144,"links":{},"metadata":{"_buckets":{"deposit":"1c6603b9-1446-4074-9b73-09a5ea26cf3d"},"_deposit":{"id":"30144","owners":[],"pid":{"revision_id":0,"type":"depid","value":"30144"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00030144","sets":["320:321:322"]},"author_link":["99507","99508","99509","99510"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-02-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"387","bibliographicPageStart":"383","bibliographicVolumeNumber":"39","bibliographic_titles":[{"bibliographic_title":"Organometallics","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Reactions of boron- and nitrogen-substituted acetylene toward hydro-/chloroboranes are described. The X-ray crystallography revealed the formation of BCBH/BCBCl four-membered rings in the solid state. By NMR and IR spectroscopic analysis, the BCBH four-membered ring was retained even in the solution. In contrast, the BCBCl four-membered ring exists as an association/dissociation equilibrium mixture in solution. The B–H–B moiety forms a three-center-two-electron bond through a spherical 1s orbital of a hydrogen atom; therefore, the four-membered ring does not have significant strain. On the other hand, due to the weak coordination bond from Cl to B, the BCBCl four-membered ring was labile. In addition, the rearrangement of the BCBH ring under heating conditions is described.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021-02-10","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.organomet.9b00876","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-wR8MIvpG8vJuy3xUTpUS].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0276-7333","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kobayashi, Akemi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99507","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Katsunori","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99508","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kitamura, Ryo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99509","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamashita, Makoto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"99510","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-02-10"}],"displaytype":"detail","filename":"om-2019-00876nR1_marked_revised_200123.pdf","filesize":[{"value":"490.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"om-2019-00876nR1_marked_revised_200123","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/30144/files/om-2019-00876nR1_marked_revised_200123.pdf"},"version_id":"a276e408-21c5-49d6-b259-05fade509e67"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Formation of BCBH/BCBCl Four-Membered Rings by Complexation of Boron- and Nitrogen-Substituted Acetylene with Hydro-/Chloroboranes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Formation of BCBH/BCBCl Four-Membered Rings by Complexation of Boron- and Nitrogen-Substituted Acetylene with Hydro-/Chloroboranes","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-06-10"},"publish_date":"2020-06-10","publish_status":"0","recid":"30144","relation_version_is_last":true,"title":["Formation of BCBH/BCBCl Four-Membered Rings by Complexation of Boron- and Nitrogen-Substituted Acetylene with Hydro-/Chloroboranes"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:23:15.279759+00:00"}