{"_buckets": {"deposit": "ff8d0178-e49e-438b-92f5-00ef993c97f5"}, "_deposit": {"id": "30162", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30162"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030162"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-03", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "3", "bibliographicPageEnd": "264", "bibliographicPageStart": "254", "bibliographicVolumeNumber": "32", "bibliographic_titles": [{"bibliographic_title": "Chirality"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Two novel chiral dimer and trimer strands composed of m \u2010terphenyl groups linked through p \u2010diethynylbenzene units with the chiral amidine group and achiral piperazine group introduced at the terminus or center of the strands, respectively, and its complementary achiral carboxylic acid dimer and trimer were synthesized. The complementary chiral/achiral strands form an excess\u2010handed double\u2010helical structure as supported by intense split\u2010type Cotton effects in the absorption regions of the conjugated backbones biased by the chiral amidinium\u2013carboxylate salt bridges. The double\u2010helical trimer was found to catalyze the direct aldol reaction of cyclohexanone with 4\u2010nitrobenzaldehyde and produce the products with a moderate enantioselectivity despite the fact that the catalytically active bifunctional piperazine/carboxylic acid pair introduced in the middle is achiral, indicating the key role of the one\u2010handed double\u2010helical framework for supramolecular bifunctional organocatalysis.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021-03-01", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/chir.23169", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [Taura, D, Shimomura, K, Ousaka, N, Yashima, E. Complementary double\u2010stranded helical oligomers bearing achiral bifunctional groups that catalyze asymmetric aldol reaction. Chirality. 2020; 32: 254\u2013264. https://doi.org/10.1002/chir.23169], which has been published in final form at [https://doi.org/10.1002/chir.23169]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "0899-0042", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Taura, Daisuke"}], "nameIdentifiers": [{"nameIdentifier": "99595", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shimomura, Kouhei"}], "nameIdentifiers": [{"nameIdentifier": "99596", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ousaka, Naoki"}], "nameIdentifiers": [{"nameIdentifier": "99597", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yashima, Eiji"}], "nameIdentifiers": [{"nameIdentifier": "99598", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-03-01"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Yashima-final_ver.pdf", "filesize": [{"value": "10.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 10200000.0, "url": {"label": "Yashima-final_ver", "url": "https://nagoya.repo.nii.ac.jp/record/30162/files/Yashima-final_ver.pdf"}, "version_id": "d4cb5626-6c8f-4b83-a343-2130e00942bd"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "aldol reaction", "subitem_subject_scheme": "Other"}, {"subitem_subject": "complementary double helix", "subitem_subject_scheme": "Other"}, {"subitem_subject": "enantioselectivity", "subitem_subject_scheme": "Other"}, {"subitem_subject": "salt bridge", "subitem_subject_scheme": "Other"}, {"subitem_subject": "supramolecular catalysis", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Complementary double\u2010stranded helical oligomers bearing achiral bifunctional groups that catalyze asymmetric aldol reaction", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Complementary double\u2010stranded helical oligomers bearing achiral bifunctional groups that catalyze asymmetric aldol reaction"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00032348", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2020-06-11"}, "publish_date": "2020-06-11", "publish_status": "0", "recid": "30162", "relation": {}, "relation_version_is_last": true, "title": ["Complementary double\u2010stranded helical oligomers bearing achiral bifunctional groups that catalyze asymmetric aldol reaction"], "weko_shared_id": null}