{"created":"2021-03-01T06:38:38.017145+00:00","id":30326,"links":{},"metadata":{"_buckets":{"deposit":"6bf1d3c3-213d-4c92-a456-dbe691af4554"},"_deposit":{"id":"30326","owners":[],"pid":{"revision_id":0,"type":"depid","value":"30326"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00030326","sets":["320:321:322"]},"author_link":["100602","100603"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-04-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"20","bibliographicPageEnd":"4523","bibliographicPageStart":"4520","bibliographicVolumeNumber":"26","bibliographic_titles":[{"bibliographic_title":"Chemistry – A European Journal","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The reaction between a dialkyl‐substituted alumanyl anion and [Y(CH2SiMe3)2(thf)3][BPh4] resulted in the formation of (dialkylalumanyl)yttrium complex 2 , which exhibits the first 2‐center–2‐electron (2 c‐2 e) Al−Y bond. The 1H and 13C NMR spectra of 2 together with an X‐ray crystallographic analysis indicated a C 2v symmetrical structure. DFT calculations on 2 revealed that its LUMO consists of overlapping 3 p‐ and 4 d‐orbitals of the Al and Y atoms, respectively, and that the HOMO–LUMO gap is narrow. The UV/Vis spectrum of 2 exhibited a visible absorption at 432 nm, which suggests that the strong σ‐donating and π‐accepting character of the three‐coordinate dialkylalumanyl ligand generates a colored d^0‐complex that does not contain any π‐electrons.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021-04-06","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/chem.202000752","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [K. Sugita, M. Yamashita, Chem. Eur. J. 2020 , 26 , 4520.], which has been published in final form at [https://doi.org/10.1002/chem.202000752]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0947-6539","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sugita, Kengo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"100602","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamashita, Makoto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"100603","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-04-06"}],"displaytype":"detail","filename":"accepted_manucript.pdf","filesize":[{"value":"693.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"accepted_manucript","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/30326/files/accepted_manucript.pdf"},"version_id":"58b8d7de-b476-4ce8-a37d-b3fcf5988b14"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"absorption","subitem_subject_scheme":"Other"},{"subitem_subject":"alumanyl complexes","subitem_subject_scheme":"Other"},{"subitem_subject":"charge-transfer complexes","subitem_subject_scheme":"Other"},{"subitem_subject":"X-type ligands","subitem_subject_scheme":"Other"},{"subitem_subject":"yttrium","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"An Alumanylyttrium Complex with an Absorption due to a Transition from the Al−Y Bond to an Unoccupied d‐Orbital","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"An Alumanylyttrium Complex with an Absorption due to a Transition from the Al−Y Bond to an Unoccupied d‐Orbital","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-07-15"},"publish_date":"2020-07-15","publish_status":"0","recid":"30326","relation_version_is_last":true,"title":["An Alumanylyttrium Complex with an Absorption due to a Transition from the Al−Y Bond to an Unoccupied d‐Orbital"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:23:40.924357+00:00"}