{"created":"2021-03-01T06:38:38.152319+00:00","id":30328,"links":{},"metadata":{"_buckets":{"deposit":"834e6ea3-5195-4da3-9cde-1f5bbbf3b630"},"_deposit":{"id":"30328","owners":[],"pid":{"revision_id":0,"type":"depid","value":"30328"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00030328","sets":["320:321:322"]},"author_link":["100610","100611","100612"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"100","bibliographicPageStart":"91","bibliographicVolumeNumber":"58","bibliographic_titles":[{"bibliographic_title":"Journal of Polymer Science","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A series of bio‐based vinylphenols or hydroxystyrenes is prepared by simple decarboxylation of various naturally occurring cinnamic acids such as o‐, m‐, and p‐coumaric; caffeic; ferulic; and sinapinic acids, which possess hydroxy groups and other substituents at different positions on the aromatic ring. After protection of the phenolic moieties with trialkylsilyl groups, reversible addition–fragmentation chain‐transfer polymerization is accomplished with cumyl dithiobenzoate to afford various bio‐based hydroxyl‐protected polystyrenes with controlled molecular weights and narrow molecular weight distributions. Subsequent deprotection of the silyl groups under mild conditions results in a series of well‐defined functionalized polystyrenes possessing different numbers (mono‐, di‐, tri‐) of hydroxy groups at different positions (o , m , p ). The obtained functionalized polystyrenes show unique thermal properties depending on the substituents, and those with phenol and catechol groups serve as reducing agents for silver ions.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021-01-01","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/pola.29453","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [Takeshima, H., Satoh, K. and Kamigaito, M. (2020), Bio‐based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes. J. Polym. Sci., 58: 91-100. doi:10.1002/pola.29453], which has been published in final form at [https://doi.org/10.1002/pola.29453]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"2642-4150","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Takeshima, Hisaaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"100610","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Satoh, Kotaro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"100611","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kamigaito, Masami","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"100612","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-01-01"}],"displaytype":"detail","filename":"JOURNAL_OF_POLYMER_SCIENCE_58_1_2020_91-100.pdf","filesize":[{"value":"2.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JOURNAL_OF_POLYMER_SCIENCE_58_1_2020_91-100","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/30328/files/JOURNAL_OF_POLYMER_SCIENCE_58_1_2020_91-100.pdf"},"version_id":"707cfe1c-fb45-486d-a6a7-f3ea9e2a30bb"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"bio‐based polymer","subitem_subject_scheme":"Other"},{"subitem_subject":"cinnamic acid","subitem_subject_scheme":"Other"},{"subitem_subject":"hydroxystyrene","subitem_subject_scheme":"Other"},{"subitem_subject":"catechol","subitem_subject_scheme":"Other"},{"subitem_subject":"functionalization of polymers","subitem_subject_scheme":"Other"},{"subitem_subject":"gallol","subitem_subject_scheme":"Other"},{"subitem_subject":"guaiacol","subitem_subject_scheme":"Other"},{"subitem_subject":"living polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"phenol","subitem_subject_scheme":"Other"},{"subitem_subject":"RAFT","subitem_subject_scheme":"Other"},{"subitem_subject":"radical polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"syringol","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Bio‐based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Bio‐based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-07-15"},"publish_date":"2020-07-15","publish_status":"0","recid":"30328","relation_version_is_last":true,"title":["Bio‐based vinylphenol family: Synthesis via decarboxylation of naturally occurring cinnamic acids and living radical polymerization for functionalized polystyrenes"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:23:41.125002+00:00"}