{"_buckets": {"deposit": "6116cd0a-c923-434f-bdf0-5e2889e97000"}, "_deposit": {"id": "30329", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30329"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030329"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-04-20", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "17", "bibliographicPageEnd": "6838", "bibliographicPageStart": "6832", "bibliographicVolumeNumber": "59", "bibliographic_titles": [{"bibliographic_title": "Angewandte Chemie International Edition"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Thiol\u2010ene cationic and radical reactions were conducted for 1:1 addition between a thiol and vinyl ether, and also for cyclization and step\u2010growth polymerization between a dithiol and divinyl ether. p\u2010Toluenesulfonic acid (PTSA) induced a cationic thiol\u2010ene reaction to generate a thioacetal in high yield, whereas 2,2\u2032\u2010azobisisobutyronitrile resulted in a radical thiol\u2010ene reaction to give a thioether, also in high yield. The cationic and radical addition reactions between a dithiol and divinyl ether with oxyethylene units yielded amorphous poly(thioacetal)s and crystalline poly(thioether)s, respectively. Under high\u2010dilution conditions, the cationic and radical reactions resulted in 16\u2010 and 18\u2010membered cyclic thioacetal and thioether products, respectively. Furthermore, concurrent cationic and radical step\u2010growth polymerizations were realized using PTSA under UV irradiation to produce polymers having both thioacetal and thioether linkages in the main chain.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2021-04-20", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/anie.201915132", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [M. Uchiyama, M. Osumi, K. Satoh, M. Kamigaito, Angew. Chem. Int. Ed. 2020 , 59 , 6832.], which has been published in final form at [https://doi.org/10.1002/anie.201915132]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_61": {"attribute_name": "ISSN\uff08print\uff09", "attribute_value_mlt": [{"subitem_source_identifier": "1433-7851", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Uchiyama, Mineto"}], "nameIdentifiers": [{"nameIdentifier": "100613", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Osumi, Masahiro"}], "nameIdentifiers": [{"nameIdentifier": "100614", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Satoh, Kotaro"}], "nameIdentifiers": [{"nameIdentifier": "100615", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kamigaito, Masami"}], "nameIdentifiers": [{"nameIdentifier": "100616", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-04-20"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ANGEWANDTE_CHEMIE-INTERNATIONAL_EDITION_59_17_2020_6832-6838.pdf", "filesize": [{"value": "2.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2200000.0, "url": {"label": "ANGEWANDTE_CHEMIE-INTERNATIONAL_EDITION_59_17_2020_6832-6838", "url": "https://nagoya.repo.nii.ac.jp/record/30329/files/ANGEWANDTE_CHEMIE-INTERNATIONAL_EDITION_59_17_2020_6832-6838.pdf"}, "version_id": "07ddbdb3-7fa1-41f0-9f6d-1d893f272266"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "copolymers", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cyclization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "polymerization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "radicals", "subitem_subject_scheme": "Other"}, {"subitem_subject": "synthetic methods", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Thiol\u2010Ene Cationic and Radical Reactions: Cyclization, Step\u2010Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Thiol\u2010Ene Cationic and Radical Reactions: Cyclization, Step\u2010Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00032515", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2020-07-15"}, "publish_date": "2020-07-15", "publish_status": "0", "recid": "30329", "relation": {}, "relation_version_is_last": true, "title": ["Thiol\u2010Ene Cationic and Radical Reactions: Cyclization, Step\u2010Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units"], "weko_shared_id": null}