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Thiol‐Ene Cationic and Radical Reactions: Cyclization, Step‐Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units
http://hdl.handle.net/2237/00032515
http://hdl.handle.net/2237/0003251591df2f2f-d90a-45bf-b773-73c4aaf6c65a
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-07-15 | |||||
タイトル | ||||||
タイトル | Thiol‐Ene Cationic and Radical Reactions: Cyclization, Step‐Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units | |||||
言語 | en | |||||
著者 |
Uchiyama, Mineto
× Uchiyama, Mineto× Osumi, Masahiro× Satoh, Kotaro× Kamigaito, Masami |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is the peer reviewed version of the following article: [M. Uchiyama, M. Osumi, K. Satoh, M. Kamigaito, Angew. Chem. Int. Ed. 2020 , 59 , 6832.], which has been published in final form at [https://doi.org/10.1002/anie.201915132]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | copolymers | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | cyclization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | polymerization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | radicals | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | synthetic methods | |||||
抄録 | ||||||
内容記述 | Thiol‐ene cationic and radical reactions were conducted for 1:1 addition between a thiol and vinyl ether, and also for cyclization and step‐growth polymerization between a dithiol and divinyl ether. p‐Toluenesulfonic acid (PTSA) induced a cationic thiol‐ene reaction to generate a thioacetal in high yield, whereas 2,2′‐azobisisobutyronitrile resulted in a radical thiol‐ene reaction to give a thioether, also in high yield. The cationic and radical addition reactions between a dithiol and divinyl ether with oxyethylene units yielded amorphous poly(thioacetal)s and crystalline poly(thioether)s, respectively. Under high‐dilution conditions, the cationic and radical reactions resulted in 16‐ and 18‐membered cyclic thioacetal and thioether products, respectively. Furthermore, concurrent cationic and radical step‐growth polymerizations were realized using PTSA under UV irradiation to produce polymers having both thioacetal and thioether linkages in the main chain. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2021-04-20 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/anie.201915132 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1433-7851 | |||||
書誌情報 |
en : Angewandte Chemie International Edition 巻 59, 号 17, p. 6832-6838, 発行日 2020-04-20 |
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著者版フラグ | ||||||
値 | author |