{"created":"2021-03-01T06:38:38.217841+00:00","id":30329,"links":{},"metadata":{"_buckets":{"deposit":"6116cd0a-c923-434f-bdf0-5e2889e97000"},"_deposit":{"id":"30329","owners":[],"pid":{"revision_id":0,"type":"depid","value":"30329"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00030329","sets":["320:321:322"]},"author_link":["100613","100614","100615","100616"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-04-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"17","bibliographicPageEnd":"6838","bibliographicPageStart":"6832","bibliographicVolumeNumber":"59","bibliographic_titles":[{"bibliographic_title":"Angewandte Chemie International Edition","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Thiol‐ene cationic and radical reactions were conducted for 1:1 addition between a thiol and vinyl ether, and also for cyclization and step‐growth polymerization between a dithiol and divinyl ether. p‐Toluenesulfonic acid (PTSA) induced a cationic thiol‐ene reaction to generate a thioacetal in high yield, whereas 2,2′‐azobisisobutyronitrile resulted in a radical thiol‐ene reaction to give a thioether, also in high yield. The cationic and radical addition reactions between a dithiol and divinyl ether with oxyethylene units yielded amorphous poly(thioacetal)s and crystalline poly(thioether)s, respectively. Under high‐dilution conditions, the cationic and radical reactions resulted in 16‐ and 18‐membered cyclic thioacetal and thioether products, respectively. Furthermore, concurrent cationic and radical step‐growth polymerizations were realized using PTSA under UV irradiation to produce polymers having both thioacetal and thioether linkages in the main chain.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021-04-20","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201915132","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [M. Uchiyama, M. Osumi, K. Satoh, M. Kamigaito, Angew. Chem. Int. Ed. 2020 , 59 , 6832.], which has been published in final form at [https://doi.org/10.1002/anie.201915132]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"1433-7851","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Uchiyama, Mineto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"100613","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Osumi, Masahiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"100614","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Satoh, Kotaro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"100615","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kamigaito, Masami","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"100616","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-04-20"}],"displaytype":"detail","filename":"ANGEWANDTE_CHEMIE-INTERNATIONAL_EDITION_59_17_2020_6832-6838.pdf","filesize":[{"value":"2.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ANGEWANDTE_CHEMIE-INTERNATIONAL_EDITION_59_17_2020_6832-6838","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/30329/files/ANGEWANDTE_CHEMIE-INTERNATIONAL_EDITION_59_17_2020_6832-6838.pdf"},"version_id":"07ddbdb3-7fa1-41f0-9f6d-1d893f272266"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"copolymers","subitem_subject_scheme":"Other"},{"subitem_subject":"cyclization","subitem_subject_scheme":"Other"},{"subitem_subject":"polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"radicals","subitem_subject_scheme":"Other"},{"subitem_subject":"synthetic methods","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Thiol‐Ene Cationic and Radical Reactions: Cyclization, Step‐Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Thiol‐Ene Cationic and Radical Reactions: Cyclization, Step‐Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-07-15"},"publish_date":"2020-07-15","publish_status":"0","recid":"30329","relation_version_is_last":true,"title":["Thiol‐Ene Cationic and Radical Reactions: Cyclization, Step‐Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:23:38.193754+00:00"}