{"_buckets": {"deposit": "28fd67d5-bc24-4e35-893b-bdaa8a43e5fb"}, "_deposit": {"id": "30467", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "30467"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00030467", "sets": ["696"]}, "author_link": ["101352", "101353", "101354", "101355", "101356"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-06-04", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "24", "bibliographicPageStart": "245123", "bibliographicVolumeNumber": "101", "bibliographic_titles": [{"bibliographic_title": "Physical Review B", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Metal-insulator transition was microscopically investigated by orbital-resolved nuclear magnetic resonance (OR-NMR) spectroscopy in a single crystal of vanadium dioxide VO2. Observations of the anisotropic 51V Knight shift and the nuclear quadrupole frequency allow us to evaluate orbital-dependent spin susceptibility and d orbital occupations. The result is consistent with the degenerated t2g orbitals in a correlated metallic phase and the d orbital ordering in a nonmagnetic insulating phase. The predominant orbital pointing along the chain facilitates a spin-singlet formation triggering metal-insulator transition. The asymmetry of magnetic and electric hyperfine tensors suggests the d orbital reformation favored by a low-symmetry crystal field, forming a localized molecular orbital. The result highlights the cooperative electron correlation and electron-phonon coupling in Mott transition with orbital degrees of freedom.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "American Physical Society", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1103/PhysRevB.101.245123", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2020 American Physical Society", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_61": {"attribute_name": "ISSN（print）", "attribute_value_mlt": [{"subitem_source_identifier": "2469-9950", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shimizu, Yasuhiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101352", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Jin-no, Takaaki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101353", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Iwase, Fumitatsu", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101354", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Itoh, Masayuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101355", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ueda, Yutaka", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "101356", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-09-23"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "PhysRevB101_245123.pdf", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "PhysRevB101_245123", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/30467/files/PhysRevB101_245123.pdf"}, "version_id": "e834b4c2-3e24-4bc6-a1da-62dd584e55e2"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Occupation switching of d orbitals in vanadium dioxide probed via hyperfine interactions", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Occupation switching of d orbitals in vanadium dioxide probed via hyperfine interactions", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["696"], "permalink_uri": "http://hdl.handle.net/2237/00032652", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2020-09-23"}, "publish_date": "2020-09-23", "publish_status": "0", "recid": "30467", "relation": {}, "relation_version_is_last": true, "title": ["Occupation switching of d orbitals in vanadium dioxide probed via hyperfine interactions"], "weko_shared_id": -1}