{"created":"2021-03-01T06:38:47.361494+00:00","id":30467,"links":{},"metadata":{"_buckets":{"deposit":"28fd67d5-bc24-4e35-893b-bdaa8a43e5fb"},"_deposit":{"id":"30467","owners":[],"pid":{"revision_id":0,"type":"depid","value":"30467"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00030467","sets":["336:695:696"]},"author_link":["101352","101353","101354","101355","101356"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-06-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"24","bibliographicPageStart":"245123","bibliographicVolumeNumber":"101","bibliographic_titles":[{"bibliographic_title":"Physical Review B","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Metal-insulator transition was microscopically investigated by orbital-resolved nuclear magnetic resonance (OR-NMR) spectroscopy in a single crystal of vanadium dioxide VO2. Observations of the anisotropic 51V Knight shift and the nuclear quadrupole frequency allow us to evaluate orbital-dependent spin susceptibility and d orbital occupations. The result is consistent with the degenerated t2g orbitals in a correlated metallic phase and the d orbital ordering in a nonmagnetic insulating phase. The predominant orbital pointing along the chain facilitates a spin-singlet formation triggering metal-insulator transition. The asymmetry of magnetic and electric hyperfine tensors suggests the d orbital reformation favored by a low-symmetry crystal field, forming a localized molecular orbital. The result highlights the cooperative electron correlation and electron-phonon coupling in Mott transition with orbital degrees of freedom.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Physical Society","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1103/PhysRevB.101.245123","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2020 American Physical Society","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"2469-9950","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shimizu, Yasuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101352","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Jin-no, Takaaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101353","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Iwase, Fumitatsu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101354","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Itoh, Masayuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101355","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ueda, Yutaka","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101356","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-23"}],"displaytype":"detail","filename":"PhysRevB101_245123.pdf","filesize":[{"value":"1.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"PhysRevB101_245123","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/30467/files/PhysRevB101_245123.pdf"},"version_id":"e834b4c2-3e24-4bc6-a1da-62dd584e55e2"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Occupation switching of d orbitals in vanadium dioxide probed via hyperfine interactions","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Occupation switching of d orbitals in vanadium dioxide probed via hyperfine interactions","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-09-23"},"publish_date":"2020-09-23","publish_status":"0","recid":"30467","relation_version_is_last":true,"title":["Occupation switching of d orbitals in vanadium dioxide probed via hyperfine interactions"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:23:57.381915+00:00"}