{"created":"2021-03-01T06:38:50.618561+00:00","id":30516,"links":{},"metadata":{"_buckets":{"deposit":"eb521230-6546-4456-8388-e41456a0df55"},"_deposit":{"id":"30516","owners":[],"pid":{"revision_id":0,"type":"depid","value":"30516"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00030516","sets":["336:695:696"]},"author_link":["101584","101585","101586","101587","101588","101589","101590"],"control_number":"30516","item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"20","bibliographicPageEnd":"8913","bibliographicPageStart":"8908","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"The Journal of Physical Chemistry Letters","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The high-spin S2 state was investigated with photosystem II (PSII) from spinach, Thermosynechococcus vulcanus, and Cyanidioschyzon merolae. In extrinsic protein-depleted PSII, high-spin electron paramagnetic resonance (EPR) signals were not detected in either species, whereas all species showed g ∼ 5 signals in the presence of a high concentration of Ca^2+ instead of the multiline signal. In the intact and PsbP/Q-depleted PSII from spinach, the g = 4.1 EPR signal was detected. These results show that formation of the high-spin S2 state of the manganese cluster is regulated by the extrinsic proteins through a charge located near the Mn4 atom in the Mn4CaO5 cluster but is independent of the intrinsic proteins. The shift to the g ∼ 5 state is caused by tilting of the z-axis in the Mn4 coordinates through hydrogen bonds or external divalent cations. The structural modification may allow insertion of an oxygen atom during the S2-to-S3 transition.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Published online: 29 September 2020 ファイル公開：2021-09-29","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.jpclett.0c02411","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Physical Chemistry B], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-UCBYCVYETEJEWMH7QIBW].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"1948-7185","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Taguchi, Shota","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101584","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shen, Liangliang","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101585","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Han, Guangye","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101586","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Umena, Yasufumi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101587","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shen, Jian-Ren","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101588","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Noguchi, Takumi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101589","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mino, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101590","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-09-29"}],"displaytype":"detail","filename":"200926_manuscript_JPCL_pr.pdf","filesize":[{"value":"927.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"200926_manuscript_JPCL_pr","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/30516/files/200926_manuscript_JPCL_pr.pdf"},"version_id":"a5dcea81-753e-4787-a53f-2b0cb6046da2"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-09-29"}],"displaytype":"detail","filename":"jz0c02411_si_001.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"jz0c02411_si_001","objectType":"dataset","url":"https://nagoya.repo.nii.ac.jp/record/30516/files/jz0c02411_si_001.pdf"},"version_id":"406f11c1-e1d9-4c98-9b5a-f48dd31c8452"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Formation of the High-Spin S2 State Related to the Extrinsic Proteins in the Oxygen Evolving Complex of Photosystem II","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Formation of the High-Spin S2 State Related to the Extrinsic Proteins in the Oxygen Evolving Complex of Photosystem II","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-10-09"},"publish_date":"2020-10-09","publish_status":"0","recid":"30516","relation_version_is_last":true,"title":["Formation of the High-Spin S2 State Related to the Extrinsic Proteins in the Oxygen Evolving Complex of Photosystem II"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:24:04.824945+00:00"}