{"created":"2021-03-01T06:38:51.945086+00:00","id":30536,"links":{},"metadata":{"_buckets":{"deposit":"0453c796-c76e-4ff9-b1f4-e6311a80da07"},"_deposit":{"id":"30536","owners":[],"pid":{"revision_id":0,"type":"depid","value":"30536"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00030536","sets":["320:321:322"]},"author_link":["101631","101632"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-06-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"11","bibliographicPageEnd":"2129","bibliographicPageStart":"2125","bibliographicVolumeNumber":"39","bibliographic_titles":[{"bibliographic_title":"Organometallics","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A reaction of dialkylalumanylpotassium with Ti(O^iPr)4 was investigated. The alumanyl anion worked as a reducing reagent to afford the trivalent titanium complex as a contact ion pair with aluminate anion probably via single-electron transfer. The ESR spectrum revealed the delocalization of an unpaired electron over Ti and Al atoms. The DFT calculations provided information about the ratio of unpaired electrons on Ti and Al atoms and the UV–vis absorption spectrum.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021-06-08","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.organomet.0c00177","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-GYPWGX8TPQK8VPMTVQUT].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0276-7333","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sugita, Kengo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101631","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamashita, Makoto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101632","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-06-08"}],"displaytype":"detail","filename":"Text_20200501.pdf","filesize":[{"value":"982.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Text_20200501","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/30536/files/Text_20200501.pdf"},"version_id":"c1b57e86-69d7-49ab-a3b1-13d331bd263d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Transfer reactions","subitem_subject_scheme":"Other"},{"subitem_subject":"Anions","subitem_subject_scheme":"Other"},{"subitem_subject":"Absorption","subitem_subject_scheme":"Other"},{"subitem_subject":"Electron paramagnetic resonance spectroscopy","subitem_subject_scheme":"Other"},{"subitem_subject":"Absorption spectroscopy","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-10-13"},"publish_date":"2020-10-13","publish_status":"0","recid":"30536","relation_version_is_last":true,"title":["One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:24:07.960867+00:00"}