{"created":"2021-03-01T06:38:52.342922+00:00","id":30542,"links":{},"metadata":{"_buckets":{"deposit":"f580e141-beb9-4ae0-84a4-8776de21af34"},"_deposit":{"id":"30542","owners":[],"pid":{"revision_id":0,"type":"depid","value":"30542"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00030542","sets":["320:321:322"]},"author_link":["101686","101687","101688"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-06-19","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"4892","bibliographicPageStart":"4888","bibliographicVolumeNumber":"22","bibliographic_titles":[{"bibliographic_title":"Organic Letters","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The halogen-bonding interaction between I2 and N-iodosuccinimide (NIS) stabilized by a Lewis base (LB) has been explored. 1H NMR, nuclear Overhauser effect (NOE), and diffusion-ordered NMR spectroscopy (DOSY) suggest the generation of a 1:1:1 assembly, LB–I2–NIS. In contrast, when N-iodotrifluoromethanesulfonimide (INTf2) is used instead of NIS, LB–I5^+–LB is generated. On the basis of these results in combination with density functional theory (DFT) calculations, we propose a mechanism for the formation of I2–NIS and the subsequent generation of an active iodinating species LB–I^+.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021-06-19","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.orglett.0c01735","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-3IRZKRT9IWGWNK2ERFHP].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"1523-7060","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Horibe, Takahiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101686","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tsuji, Yasutaka","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101687","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishihara, Kazuaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"101688","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-06-19"}],"displaytype":"detail","filename":"2nd_revised_manuscript.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"2nd_revised_manuscript","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/30542/files/2nd_revised_manuscript.pdf"},"version_id":"5671c2cc-91c9-46b5-a27e-5cf243a72916"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Iodine","subitem_subject_scheme":"Other"},{"subitem_subject":"Reagents","subitem_subject_scheme":"Other"},{"subitem_subject":"Halogen bonding","subitem_subject_scheme":"Other"},{"subitem_subject":"Lewis bases","subitem_subject_scheme":"Other"},{"subitem_subject":"Cations","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Halogen-Bonding Interaction between I2 and N-Iodosuccinimide in Lewis Base-Catalyzed Iodolactonization","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Halogen-Bonding Interaction between I2 and N-Iodosuccinimide in Lewis Base-Catalyzed Iodolactonization","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-10-14"},"publish_date":"2020-10-14","publish_status":"0","recid":"30542","relation_version_is_last":true,"title":["Halogen-Bonding Interaction between I2 and N-Iodosuccinimide in Lewis Base-Catalyzed Iodolactonization"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:24:08.119352+00:00"}