@article{oai:nagoya.repo.nii.ac.jp:00031015, author = {Ohki, Yasuhiro and Ishihara, Kodai and Yaoi, Moeko and Tada, Mizuki and Sameera, W. M. C. and Cramer, Roger E.}, issue = {58}, journal = {Chemical Communications}, month = {Jul}, note = {Hydride-bridged transition metal complexes have been found to serve as suitable precursors for the activation of small molecules without the use of reducing agents. In this study, we synthesized a dinuclear Mo2H8 complex supported by bulky C5H2tBu3 (Cp‡) ligands, Cp‡2Mo2H8 (1), from the reaction of Cp‡MoCl4 with KC8 under H2. The hydrides of complex 1 can be replaced with benzene at 60 °C to afford a μ-benzene complex Cp‡2Mo2H2(μ-C6H6) (2)., ファイル公開:2021/07/25}, pages = {8035--8038}, title = {A dinuclear Mo2H8 complex supported by bulky C5H2tBu3 ligands}, volume = {56}, year = {2020} }