{"created":"2021-03-01T06:39:24.700904+00:00","id":31028,"links":{},"metadata":{"_buckets":{"deposit":"84b01bea-170d-4840-ae5e-6c60df31c813"},"_deposit":{"id":"31028","owners":[],"pid":{"revision_id":0,"type":"depid","value":"31028"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00031028","sets":["320:321:322"]},"author_link":["102598","102599","102600","102601","102602"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-07-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"27","bibliographicPageEnd":"11668","bibliographicPageStart":"11663","bibliographicVolumeNumber":"142","bibliographic_titles":[{"bibliographic_title":"Journal of the American Chemical Society","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The synthesis and properties of dinaphtho[1,8-bc:1′,8′-ef]thiepine bisimide (DNTBI) and its oxides are described. Their molecular design is conceptually based on the insertion of a sulfur atom into the perylene bisimide (PBI) core. These sulfur-inserted PBI derivatives adopt nonplanar structures, which significantly increases their solubility in common organic solvents. Upon electron injection, light irradiation, or heating, DNTBI and its sulfoxides undergo sulfur extrusion reactions to furnish PBI. The photoinduced and thermal sulfur extrusion reactions proceed almost quantitatively. This unique reactivity enabled the fabrication of a high-performance solution-processed n-type organic field-effect transistor with an electron mobility of up to 0.41 cm2 V^–1 s^–1.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021-07-08 ","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/jacs.0c04096","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-UAQW5QIWQQSFCX7RRSQI].” ","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0002-7863","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hayakawa, Sakiho","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102598","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsuo, Kyohei","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102599","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamada, Hiroko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102600","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukui, Norihito","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102601","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shinokubo, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102602","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-07-08"}],"displaytype":"detail","filename":"S-PBI_MS_0605.pdf","filesize":[{"value":"3.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"S-PBI_MS_0605","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/31028/files/S-PBI_MS_0605.pdf"},"version_id":"8dffa1cf-a109-4a87-a5da-573fa6a5f7d3"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Dinaphthothiepine Bisimide and Its Sulfoxide: Soluble Precursors for Perylene Bisimide","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Dinaphthothiepine Bisimide and Its Sulfoxide: Soluble Precursors for Perylene Bisimide","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-12-17"},"publish_date":"2020-12-17","publish_status":"0","recid":"31028","relation_version_is_last":true,"title":["Dinaphthothiepine Bisimide and Its Sulfoxide: Soluble Precursors for Perylene Bisimide"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:24:32.145390+00:00"}