{"created":"2021-03-01T06:39:24.969150+00:00","id":31032,"links":{},"metadata":{"_buckets":{"deposit":"59139db1-67b2-42cd-b714-c9d7b6a0eeec"},"_deposit":{"id":"31032","owners":[],"pid":{"revision_id":0,"type":"depid","value":"31032"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00031032","sets":["320:321:322"]},"author_link":["102622","102623","102624","102625","102626","102627","102628","102629"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-08-18","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"1183","bibliographicPageStart":"1178","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"ACS Macro Letters","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Carvone, a naturally abundant chiral cyclic α,β-unsaturated carbonyl compound, was chemically transformed into cyclic exo-methylene conjugated dienes. The exo-methylene group had high reactivity in cationic polymerization and was efficiently polymerized in a controlled manner via regioselective 1,4-conjugated additions using initiating systems effective for living cationic polymerization of vinyl ethers. The obtained polymers with 1,3-cyclohexenyl units and tetra-substituted olefins in the main chain showed high glass transition temperatures over 110 °C. The chiral monomer underwent stereospecific polymerization to result in polymers with low solubility and weak packing of the rigid main chain in the lamellar layers. The racemic mixture resulted in soluble amorphous polymers, which were subsequently hydrogenated into cycloolefin polymers with enhanced thermal properties.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2021-08-18","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Springer","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acsmacrolett.0c00479","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Macro Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-HEKMBPCEYXAUHBFV4ZGQ].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"2161-1653","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nishida, Takenori","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102622","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Satoh, Kotaro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102623","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nagano, Shusaku","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102624","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Seki, Takahiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102625","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tamura, Masazumi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102626","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Li, Yingai","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102627","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tomishige, Keiichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102628","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kamigaito, Masami","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"102629","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-08-18"}],"displaytype":"detail","filename":"ACS_MACRO_LETTERS_9_8_2020_1178-1183.pdf","filesize":[{"value":"22.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ACS_MACRO_LETTERS_9_8_2020_1178-1183","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/31032/files/ACS_MACRO_LETTERS_9_8_2020_1178-1183.pdf"},"version_id":"ae2a62b1-3725-4a4f-9513-9c86978d986b"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Biobased Cycloolefin Polymers: Carvone-Derived Cyclic Conjugated Diene with Reactive exo-Methylene Group for Regioselective and Stereospecific Living Cationic Polymerization","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Biobased Cycloolefin Polymers: Carvone-Derived Cyclic Conjugated Diene with Reactive exo-Methylene Group for Regioselective and Stereospecific Living Cationic Polymerization","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-12-18"},"publish_date":"2020-12-18","publish_status":"0","recid":"31032","relation_version_is_last":true,"title":["Biobased Cycloolefin Polymers: Carvone-Derived Cyclic Conjugated Diene with Reactive exo-Methylene Group for Regioselective and Stereospecific Living Cationic Polymerization"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:24:32.217502+00:00"}