{"created":"2021-03-01T06:12:01.017446+00:00","id":5454,"links":{},"metadata":{"_buckets":{"deposit":"bea90cf8-607a-4592-8999-497b62ff4584"},"_deposit":{"id":"5454","owners":[],"pid":{"revision_id":0,"type":"depid","value":"5454"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00005454","sets":["336:695:696"]},"author_link":["14048","14049","14050","14051","14052"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2000-12-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"21","bibliographicPageEnd":"9597","bibliographicPageStart":"9593","bibliographicVolumeNumber":"113","bibliographic_titles":[{"bibliographic_title":"The Journal of Chemical Physics","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The oxidation states of Sm atoms in various fullerene cages are directly investigated by electron energy-loss spectroscopy. The observed peak positions of the M_45 edges of the Sm atom in Sm@C_2n [2n=74, 78, 80, 82 (isomers I, III), 84 (isomers I, II, III)] are apparently shifted to the lower binding energy region in comparison with those of a trivalent Sm^3+ in Sm_2O_3. The results indicate that the Sm atoms take +2 valence states irrespective of the fullerene cages. This observation is discussed based on a simple thermochemical cycle model. We also report that the Sm metallofullerenes have been converted to Sm carbide materials under a prolonged electron beam irradiation.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/7059"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Institute of Physics","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1063/1.1321047","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (2000) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0021-9606","subitem_source_identifier_type":"PISSN"}]},"item_10_text_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_text_value":"application/pdf"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Okazaki, Toshiya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14048","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suenaga, Kazutomo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14049","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lian, Yongfu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14050","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Gu, Zhennan","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14051","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shinohara, Hisanori","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"14052","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-02-19"}],"displaytype":"detail","filename":"JChemPhys_113_9593.pdf","filesize":[{"value":"85.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JChemPhys_113_9593.pdf","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/5454/files/JChemPhys_113_9593.pdf"},"version_id":"cf28b52d-5054-4d00-abd4-8f7f877c8a2a"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Direct EELS observation of the oxidation states of Sm atoms in Sm@C_2n metallofullerenes (74 ≼ 2n ≼ 84)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Direct EELS observation of the oxidation states of Sm atoms in Sm@C_2n metallofullerenes (74 ≼ 2n ≼ 84)","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2006-10-25"},"publish_date":"2006-10-25","publish_status":"0","recid":"5454","relation_version_is_last":true,"title":["Direct EELS observation of the oxidation states of Sm atoms in Sm@C_2n metallofullerenes (74 ≼ 2n ≼ 84)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T03:50:02.993565+00:00"}