@article{oai:nagoya.repo.nii.ac.jp:00005487, author = {Kimura, Takumi and Sugai, Toshiki and Shinohara, Hisanori}, issue = {19}, journal = {The Journal of Chemical Physics}, month = {May}, note = {We report the first results of surface collisions of pure hollow fullerenes (C_60, C_70 and C_78) and endohedral metallofullerenes (Y@C_82, Ca@C_82 and Ca@C_84), isolated by liquid chromatography, against solid (silicon and gold) surfaces and self-assembled monolayer (SAM) films. The experiments have been performed by a reflectron type time-of-flight mass spectrometer modified for measuring surface-induced dissociation (SID) spectra. No surface-induced fragment is observed for the surface collisions with the solid surfaces and the alkanethiolate SAM film. In contrast, sequential C_2-loss fragments have been observed for the surface collisions of hollow fullerenes and Ca@C_84 with the fluorinated SAM film.}, pages = {9681--9687}, title = {Surface-induced fragmentation of higher fullerenes and endohedral metallofullerenes}, volume = {110}, year = {1999} }