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  1. B100 理学部/理学研究科
  2. B100a 雑誌掲載論文
  3. 学術雑誌

Effect of encapsulated atoms on the electronic structure of the fullerene cage: A case study on La2@C78 and Ti2C2@C78 via ultraviolet photoelectron spectroscopy

http://hdl.handle.net/2237/8838
http://hdl.handle.net/2237/8838
1882b430-0089-4e8d-9ae8-c6085f06d5a5
名前 / ファイル ライセンス アクション
PhysRevB_75-125418.pdf PhysRevB_75-125418.pdf (470.8 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2007-10-15
タイトル
タイトル Effect of encapsulated atoms on the electronic structure of the fullerene cage: A case study on La2@C78 and Ti2C2@C78 via ultraviolet photoelectron spectroscopy
言語 en
著者 Hino, Shojun

× Hino, Shojun

WEKO 19375

en Hino, Shojun

Search repository
Kato, Masayuki

× Kato, Masayuki

WEKO 19376

en Kato, Masayuki

Search repository
Yoshimura, Daisuke

× Yoshimura, Daisuke

WEKO 19377

en Yoshimura, Daisuke

Search repository
Moribe, Hiroe

× Moribe, Hiroe

WEKO 19378

en Moribe, Hiroe

Search repository
Umemoto, Hisashi

× Umemoto, Hisashi

WEKO 19379

en Umemoto, Hisashi

Search repository
Ito, Yasuhiro

× Ito, Yasuhiro

WEKO 19380

en Ito, Yasuhiro

Search repository
Sugai, Toshiki

× Sugai, Toshiki

WEKO 19381

en Sugai, Toshiki

Search repository
Shinohara, Hisanori

× Shinohara, Hisanori

WEKO 19382

en Shinohara, Hisanori

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Otani, Minoru

× Otani, Minoru

WEKO 19383

en Otani, Minoru

Search repository
Yoshimoto, Yoshihide

× Yoshimoto, Yoshihide

WEKO 19384

en Yoshimoto, Yoshihide

Search repository
Okada, Susumu

× Okada, Susumu

WEKO 19385

en Okada, Susumu

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 Copyright: American Physical Society, All rights reserved.
抄録
内容記述 Ultraviolet photoelectron spectra (UPS) of metallofullerene, La2@C78 were measured using a synchrotronradiation light source. Its spectral onset energy was 0.70 eV below the Fermi level, indicating the semiconductive nature of this metallofullerene. The UPS consisted of numerous crests and troughs. Further, a change in intensity upon tuning the excitation energy was observed; however, the intensity of the change was not as large as those observed for other fullerenes. The UPS of La2@C78 differ considerably from those of Ti2C2@C78, although they are thought to have the same cage structure. Herein, this difference is explored using density-functional theory, and the origin of this difference was determined to be the hybridization of the π-electron wave functions.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 American Physical Society
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1103/PhysRevB.75.125418
ISSN
収録物識別子タイプ PISSN
収録物識別子 1098-0121
書誌情報 en : PHYSICAL REVIEW B

巻 75, 号 12, p. 125418-125418, 発行日 2007-03
フォーマット
application/pdf
著者版フラグ
値 publisher
URI
識別子 http://hdl.handle.net/2237/8838
識別子タイプ HDL
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