{"_buckets": {"deposit": "6d2250b1-5d32-42fa-a8d1-2673f9ab0df8"}, "_deposit": {"id": "7162", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "7162"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00007162"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007-03", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "12", "bibliographicPageEnd": "125418", "bibliographicPageStart": "125418", "bibliographicVolumeNumber": "75", "bibliographic_titles": [{"bibliographic_title": "PHYSICAL REVIEW B"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Ultraviolet photoelectron spectra (UPS) of metallofullerene, La2@C78 were measured using a synchrotronradiation light source. Its spectral onset energy was 0.70 eV below the Fermi level, indicating the semiconductive nature of this metallofullerene. The UPS consisted of numerous crests and troughs. Further, a change in intensity upon tuning the excitation energy was observed; however, the intensity of the change was not as large as those observed for other fullerenes. The UPS of La2@C78 differ considerably from those of Ti2C2@C78, although they are thought to have the same cage structure. Herein, this difference is explored using density-functional theory, and the origin of this difference was determined to be the hybridization of the \u03c0-electron wave functions.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/8838"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "American Physical Society"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1103/PhysRevB.75.125418", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Copyright: American Physical Society, All rights reserved."}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1098-0121", "subitem_source_identifier_type": "ISSN"}]}, "item_10_text_14": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8", "attribute_value_mlt": [{"subitem_text_value": "application/pdf"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hino, Shojun"}], "nameIdentifiers": [{"nameIdentifier": "19375", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kato, Masayuki"}], "nameIdentifiers": [{"nameIdentifier": "19376", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yoshimura, Daisuke"}], "nameIdentifiers": [{"nameIdentifier": "19377", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Moribe, Hiroe"}], "nameIdentifiers": [{"nameIdentifier": "19378", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Umemoto, Hisashi"}], "nameIdentifiers": [{"nameIdentifier": "19379", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ito, Yasuhiro"}], "nameIdentifiers": [{"nameIdentifier": "19380", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sugai, Toshiki"}], "nameIdentifiers": [{"nameIdentifier": "19381", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shinohara, Hisanori"}], "nameIdentifiers": [{"nameIdentifier": "19382", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Otani, Minoru"}], "nameIdentifiers": [{"nameIdentifier": "19383", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yoshimoto, Yoshihide"}], "nameIdentifiers": [{"nameIdentifier": "19384", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okada, Susumu"}], "nameIdentifiers": [{"nameIdentifier": "19385", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-02-19"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "PhysRevB_75-125418.pdf", "filesize": [{"value": "470.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 470800.0, "url": {"label": "PhysRevB_75-125418.pdf", "url": "https://nagoya.repo.nii.ac.jp/record/7162/files/PhysRevB_75-125418.pdf"}, "version_id": "247080bf-81aa-41d1-b98d-6db974efafde"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Effect of encapsulated atoms on the electronic structure of the fullerene cage: A case study on La2@C78 and Ti2C2@C78 via ultraviolet photoelectron spectroscopy", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Effect of encapsulated atoms on the electronic structure of the fullerene cage: A case study on La2@C78 and Ti2C2@C78 via ultraviolet photoelectron spectroscopy"}]}, "item_type_id": "10", "owner": "1", "path": ["336/695/696"], "permalink_uri": "http://hdl.handle.net/2237/8838", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2007-10-15"}, "publish_date": "2007-10-15", "publish_status": "0", "recid": "7162", "relation": {}, "relation_version_is_last": true, "title": ["Effect of encapsulated atoms on the electronic structure of the fullerene cage: A case study on La2@C78 and Ti2C2@C78 via ultraviolet photoelectron spectroscopy"], "weko_shared_id": 3}