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Simple Models for Chirality Conversion of Crystals and Molecules by Grinding
http://hdl.handle.net/2237/13865
http://hdl.handle.net/2237/138658a8efaba-d5de-47e9-9ea7-777bd95a87a3
名前 / ファイル | ライセンス | アクション |
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uwaha-k08jpsj.pdf (213.3 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2010-07-21 | |||||
タイトル | ||||||
タイトル | Simple Models for Chirality Conversion of Crystals and Molecules by Grinding | |||||
言語 | en | |||||
著者 |
Uwaha, Makio
× Uwaha, Makio |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | ja | |||||
権利情報 | 社団法人日本物理学会 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | chirality | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | crystallization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | enantiomer | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | dynamical symmetry breaking | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | chiral cluster | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | autocatalysis | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | amino acid derivative | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | NaClO_3 | |||||
抄録 | ||||||
内容記述 | By grinding crystals in a solution, the chirality conversion of the crystal structure and the resultant conversion of molecular chirality have been realized recently. Reaction-type models that enable the reproduction of these phenomena are studied. In the models, chiral clusters are assumed to be formed by grinding and that these clusters can be integrated into crystals of the same chirality. An initial chirality imbalance is amplified exponentially, and the rate is approximately proportional to the grinding strength and to the molecular racemization rate in a relevant parameter range. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | The Physical Society of Japan | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
関連情報 | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | URI | |||||
関連識別子 | http://jpsj.ipap.jp/link?JPSJ/77/083802/ | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 00319015 | |||||
書誌情報 |
en : Journal of the Physical Society of Japan 巻 77, 号 8, p. 083802, 発行日 2008-07-25 |
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フォーマット | ||||||
application/pdf | ||||||
著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/13865 | |||||
識別子タイプ | HDL | |||||
URI | ||||||
識別子 | http://jpsj.ipap.jp/link?JPSJ/77/083802/ | |||||
識別子タイプ | URI |