{"_buckets": {"deposit": "1606d03e-0d3f-4fdd-b6ac-c9ee0514220c"}, "_deposit": {"id": "11992", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11992"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00011992", "sets": ["696"]}, "author_link": ["37962", "37963"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2009-02-10", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2", "bibliographicPageStart": "023601", "bibliographicVolumeNumber": "78", "bibliographic_titles": [{"bibliographic_title": "Journal of the Physical Society of Japan", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "It has been found that the simple grinding of crystals in a solution causes the conversion of the chiral structure of crystals and, in the case of organic molecules, the resultant conversion of molecular chirality. In order to clarify the mechanism of the chirality conversion, we study the change in the size distribution of chiral clusters in a Becker-D¨oring type model, in which chiral dimer reaction and grinding are implemented. In the absence of grinding, Ostwald ripening may cause chirality conversion if the initial size distribution is appropriate. With grinding crystals, the crystallization of chiral clusters causes an exponential amplification of the initial chiral imbalance resulting in a homochiral state. During chirality conversion, the total size distribution does not change.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/13866"}, {"subitem_identifier_type": "URI", "subitem_identifier_uri": "http://jpsj.ipap.jp/link?JPSJ/78/023601/"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "The Physical Society of Japan", "subitem_publisher_language": "en"}]}, "item_10_relation_43": {"attribute_name": "関連情報", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://jpsj.ipap.jp/link?JPSJ/78/023601/", "subitem_relation_type_select": "URI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "社団法人日本物理学会", "subitem_rights_language": 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"nameIdentifiers": [{"nameIdentifier": "37962", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Katsuno, Hiroyasu", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "37963", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-02-20"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "uwaha-k09jpsj_teisei.pdf", "filesize": [{"value": "41.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 41900.0, "url": {"label": "uwaha-k09jpsj_teisei.pdf ", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/11992/files/uwaha-k09jpsj_teisei.pdf"}, "version_id": "b5ec28cb-06e3-4a97-ad69-1896e6c0d758"}, {"accessrole": "open_date", "date": 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{"subitem_subject": "chiral cluster", "subitem_subject_scheme": "Other"}, {"subitem_subject": "autocatalysis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "NaClO_3", "subitem_subject_scheme": "Other"}, {"subitem_subject": "racemization", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Mechanism of Chirality Conversion by Grinding Crystals -Ostwald Ripening vs Crystallization of Chiral Clusters-", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Mechanism of Chirality Conversion by Grinding Crystals -Ostwald Ripening vs Crystallization of Chiral Clusters-", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["696"], "permalink_uri": "http://hdl.handle.net/2237/13866", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2010-07-21"}, "publish_date": "2010-07-21", "publish_status": "0", "recid": "11992", "relation": {}, "relation_version_is_last": true, "title": ["Mechanism of Chirality Conversion by Grinding Crystals -Ostwald Ripening vs Crystallization of Chiral Clusters-"], "weko_shared_id": -1}