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Electrochemical and Structural Properties of a 4.7 V-Class LiNi0.5Mn1.5 O 4 Positive Electrode Material Prepared with a Self-Reaction Method
http://hdl.handle.net/2237/18424
http://hdl.handle.net/2237/1842443734e87-a0df-4b93-a1f2-69f88dd394be
名前 / ファイル | ライセンス | アクション |
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J_Electrochem_Soc_2004-Takahashi-A173-7.pdf (174.0 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2013-08-28 | |||||
タイトル | ||||||
タイトル | Electrochemical and Structural Properties of a 4.7 V-Class LiNi0.5Mn1.5 O 4 Positive Electrode Material Prepared with a Self-Reaction Method | |||||
言語 | en | |||||
著者 |
Takahashi, Koh
× Takahashi, Koh× Saitoh, Motoharu× Sano, Mitsuru× Fujita, Miho× Kifune, Koichi |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | © The Electrochemical Society, Inc. 2003. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in Journal of The Electrochemical Society. v.151, n.1, 2004, p.A173-A177. | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | lithium compounds | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | electrochemical electrodes | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | heat treatment | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | powder technology | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | ceramics | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | crystal structure | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | secondary cells | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | X-ray diffraction | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | voltammetry (chemical analysis) | |||||
抄録 | ||||||
内容記述 | LiNi0.5Mn1.5O4 as 4.7 V-class cathode materials were prepared with our self-reaction method at 650, 700, and 750°C calcination temperatures respectively, and their electrochemical properties and crystal structures were studied. The sample at 700°C was assigned to the space group P4332 in the X-ray diffraction analysis. On the contrary, the space group of the sample calcined at 650 or 750°C fell into Fd3m because diffraction peaks from P4332 were missing. The sample at 700°C showed a one-step profile in the charge/discharge curve and this contrasted with the other samples showing two-step ones. In spite of their different structures, these three samples had the same initial capacities of about 123 mAh/g. They gave similarly good cycle performance as well, but the sample at 650 or 750°C maintained a little higher capacity after 50 cycles of charge/discharge than the sample at 700°C. From the analysis of transformation of the crystal structure of LiNi0.5Mn1.5O4 during charging, it was found that LiNi0.5Mn1.5O4 underwent the electrochemical reactions at three stages unlike LiMn2O4 with two stages. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | The Electrochemical Society | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1149/1.1633267 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0013-4651 | |||||
書誌情報 |
en : Journal of The Electrochemical Society 巻 151, 号 1, p. A173-A177, 発行日 2004 |
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著者版フラグ | ||||||
値 | publisher | |||||
URI | ||||||
識別子 | http://dx.doi.org/10.1149/1.1633267 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/18424 | |||||
識別子タイプ | HDL |